30926-00-2Relevant articles and documents
Cascade One-Pot Synthesis of Orange-Red-Fluorescent Polycyclic Cinnolino[2,3-f]phenanthridin-9-ium Salts by Palladium(II)-Catalyzed C?H Bond Activation of 2-Azobiaryl Compounds and Alkenes
Jayakumar, Jayachandran,Vedarethinam, Guganchandar,Hsiao, Huan-Chang,Sun, Shang-You,Chuang, Shih-Ching
, p. 689 - 694 (2019/11/22)
Quaternary ammonium salts were synthesized in moderate to good yields through double oxidative C?H bond activation on azobenzenes. The mechanism of the highly regioselective reaction of 2-azobiaryls with alkenes to give orange-red-fluorescent cinnolino[2,
Catalytic Nitrene Homocoupling by an Iron(II) Bis(alkoxide) Complex: Bulking Up the Alkoxide Enables a Wider Range of Substrates and Provides Insight into the Reaction Mechanism
Yousif, Maryam,Wannipurage, Duleeka,Huizenga, Caleb D.,Washnock-Schmid, Elizabeth,Peraino, Nicholas J.,Ozarowski, Andrew,Stoian, Sebastian A.,Lord, Richard L.,Groysman, Stanislav
supporting information, p. 9425 - 9438 (2018/08/17)
The reaction of HOR′ (OR′ = di-t-butyl-(3,5-diphenylphenyl)methoxide) with an iron(II) amide precursor forms the iron(II) bis(alkoxide) complex Fe(OR′)2(THF)2 (2). 2 (5-10 mol %) serves as a catalyst for the conversion of aryl azides
Oxidative dimerization of (hetero)aromatic amines utilizing t-BuOI leading to (hetero)aromatic azo compounds: Scope and mechanistic studies
Okumura, Sota,Lin, Chun-Hsuan,Takeda, Youhei,Minakata, Satoshi
, p. 12090 - 12105 (2014/01/06)
A straightforward synthetic method of both symmetric and unsymmetric aromatic azo compounds through an efficient and cross-selective oxidative dimerization of aromatic amines using tert-butyl hypoiodite (t-BuOI) under metal-free and mild conditions has been developed. This method was also found applicable to the synthesis of heteroaromatic azo compounds. The spectroscopic study indicates the involvement of N,N-diiodoanilines in the oxidative reaction as the key intermediate.
