31053-93-7Relevant articles and documents
Reactivity of perfluoro-n-alkyl radicals a Hammett study of hydrogen transfer from arene thiols
Dolbier Jr., William R.,Rong, Xiao X.
, p. 6225 - 6228 (1994)
A Hammett study of hydrogen atom abstraction by the perfluoro-n-heptyl radical is presented. Excellent correlation of the rates with σ+, with a ρ+ value of -0.56, provides important corroboration of the substantial influence of transition state polar effects on this unexpectedly slow process.
Control of intramolecular orbital alignment in the photodissociation of thiophenol: Conformational manipulation by chemical substitution
Lim, Jeong Sik,Lee, Yoon Sup,Kim, Sang Kyu
, p. 1853 - 1856 (2008/12/22)
(Graph Presented) Intramolecular orbital alignment can be controlled by conformational tuning of the initial wavepacket location on the two-dimensional potential-energy surfaces of thiophenol (see picture; CI = conical intersection). Chemical substitution induces conformational preference, leading to a dramatic change of the branching ratio between X and A states of the phenylthiyl radical.
Localized electron transfer in nonpoiar solution: reaction of phenols and thiophenols with free solvent radical cations
Brede, Ortwin,Ganapathi, Mahalaxmi R.,Naumov, Sergej,Naumann, Wolfgang,Hermann, Ralf
, p. 3757 - 3764 (2007/10/03)
Free electron transfer (FET) is understood as the reaction of free and uncorrelated solvent parent radical cations with solutes characterized by a lower ionization potential than those of the solvent. We studied electron transfer from phenols and thiophen
