3117-63-3

Basic information

• Product Name: N-(2-hydroxy-3-methoxybenzylidene)aniline
• Synonyms: N-(2-hydroxy-3-methoxybenzylidene)aniline
• CAS NO: 3117-63-3
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.26
• Mol File: 3117-63-3.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 394°C at 760 mmHg
• Flash Point: 192.1°C
• Appearance: /
• Density: 1.17g/cm³
• Vapor Pressure: 2.04E-06mmHg at 25°C
• Refractive Index: 1.604
• CAS DataBase Reference: N-(2-hydroxy-3-methoxybenzylidene)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-hydroxy-3-methoxybenzylidene)aniline(3117-63-3)
• EPA Substance Registry System: N-(2-hydroxy-3-methoxybenzylidene)aniline(3117-63-3)

Safety Data

• Hazardous Substances Data: 3117-63-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO2/c1-17-13-9-5-6-11(14(13)16)10-15-12-7-3-2-4-8-12/h2-10,15H,1H3/b11-10+

Upstream product

• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 98-95-3 nitrobenzene 
• 62-53-3 aniline 

Downstream Products

• 17668-28-9 bis(2-methoxy-6-((phenylimino)methyl)phenolato)copper(II) 
• 18449-03-1 bis(3-methoxy-N-phenylsalicylaldiminato)cobalt(II) 
• 3526-40-7 2-hydroxy-3-methoxy-N-phenylbenzenemethanamine 
• 303089-82-9 RuBr₂(PPh₃)2(2-O-3-OMe-C₆H₃CHNPh) 
• 303089-81-8 RuBr₂(AsPh₃)2(2-O-3-OMe-C₆H₃CHNPh) 

Relevant articles and documents

The effect of ligand design on the structural and photophysical properties of Nd(III) complexes with Schiff bases of the [(phenylimino)methyl]phenol-type

Three mononuclear Nd(III) complexes [Nd(HL1)2(NO3)3] (1, HL1=2-methoxy-6-[(E)-(phenylimino)methyl]phenol), [Nd(HL2)3(NO3)3] (2, HL2=5-methoxy-2-[

Vibrational analysis and physical property studies of 6-Methoxy-2-[(E)-phenyliminomethyl]-phenol in the THz, IR and UV–visible spectral regions

Bulk single crystals of 6-Methoxy-2-[(E)-phenyliminomethyl]phenol were grown after preparing the material by Schiff base condensation of ortho-vanillin alternatively called 2-hydroxy-3-methoxybenzaldehyde and aniline. The three dimensional molecular and c

The Direct Synthesis of Imines, Benzimidazoles and Quinoxalines from Nitroarenes and Carbonyl Compounds by Selective Nitroarene Hydrogenation Employing a Reusable Iron Catalyst

The “replacement” of noble metals by earth abundant metals is a desirable aim in catalysis and a possible way of conserving rare elements. The “replacement” is especially attractive if novel selectivity patterns are observed permitting the development of novel coupling reactions. Herein, we report on a novel, robust and reusable iron catalyst, which permits the selective hydrogenation of nitroarenes in the presence of hydrogenation-sensitive functional groups. Based on the selectivity pattern observed, the direct iron-catalyzed synthesis of imines and benzimidazoles from nitroarenes and aldehydes becomes feasible. In addition, we introduce the direct synthesis of quinoxalines from nitroarenes and diketones applying our catalyst.