311806-85-6

Basic information

• Product Name: (3RS)-2-methyl-2-phenylsulfanylhex-5-en-3-ol
• Synonyms: (3RS)-2-methyl-2-phenylsulfanylhex-5-en-3-ol
• CAS NO: 311806-85-6
• Molecular Weight: 222.351
• Mol File: 311806-85-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3RS)-2-methyl-2-phenylsulfanylhex-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3RS)-2-methyl-2-phenylsulfanylhex-5-en-3-ol(311806-85-6)
• EPA Substance Registry System: (3RS)-2-methyl-2-phenylsulfanylhex-5-en-3-ol(311806-85-6)

Safety Data

• Hazardous Substances Data: 311806-85-6(Hazardous Substances Data)

Upstream product

• 63996-66-7 2-methyl-2-(phenylthio)propanal 
• 2622-05-1 allylmagnesium bromide 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 311806-87-8 2-methyl-2-phenylsulfanylhex-5-en-3-one 
• 637036-22-7 (E)-2,9-Dimethyl-2,9-bis-phenylsulfanyl-dec-5-ene-3,8-dione 

Relevant articles and documents

Thermodynamically controlled cyclisation reactions with double phenylsulfanyl migration

Enantiomerically enriched C2-symmetric tetrols were synthesised by a route involving a 'self-metathesis' reaction with Grubbs' second-generation ruthenium catalyst; these tetrols produced interesting bicyclic products when rearranged under acid

Asymmetric synthesis of tetrahydrofurans by competitive [1,2]-phenylsulfanyl (PhS) migrations under thermodynamic control

Asymmetric synthesis of tetrahydrofurans (THF) by competitive [1,2]-phenylsulfanyl (PhS) migrations under thermodynamic control was discussed. Triols were prepared in enantiomerically enriched form by a short route that included a Sharpless asymmetric dihydroxylation. Treatment of these triols with toluene-p-sulfonic acid gave THFs as thermodynamic products.