313071-21-5

Basic information

• Product Name: RuCl₃((1,4-diphenylphosphino)butane)(pyridine)
• CAS NO: 313071-21-5
• Molecular Weight: 713.008
• Mol File: 313071-21-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: RuCl₃((1,4-diphenylphosphino)butane)(pyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl₃((1,4-diphenylphosphino)butane)(pyridine)(313071-21-5)
• EPA Substance Registry System: RuCl₃((1,4-diphenylphosphino)butane)(pyridine)(313071-21-5)

Safety Data

• Hazardous Substances Data: 313071-21-5(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 243643-58-5 RuCl₃(1,4-diphenylphosphino)butane monohydrate 

Relevant articles and documents

Electrosynthesis of binuclear ruthenium complexes from [RuCl3(dppb)(L)] precursors [L = pyridine, 4-methylpyridine or dimethyl sulfoxide; dppb = l,4-bis(diphenylphosphino)butane]

Electrolysis has been examined as a method of synthesis for [(L)(dppb)Ru((i-Cl)3RuCl(dppb)] complexes, where dppb = l,4-bis(diphenylphosphino)butane and L = pyridine (py), 4-methylpyridine (4-pic) or dimethyl sulfoxide (DMSO), by using [RuCl3(dppb)(L)] as precursors. The products of the electrolysis were characterized by 31P-{'H} NMR, cyclic voltammetry and near infrared spectroscopy. The presence of the [Ru2Cl5(dppb)2] complex in the electrochemical cell suggests a mechanism by which the starting original species from the bulk solution reacts with the reduced form [RuCl2(dppb)(L)] generated at the surface of the electrode. The crystal structure of the precursor ;ner-[RuCl,(dppb)(4-pic)l was determined by X-ray diffraction; The Royal Society of Chemistry 2000.