31335-70-3Relevant articles and documents
Sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe2O3 nanocrystallites as a magnetically Br?nsted acid for N-formylation of amines
Ma'mani, Leila,Sheykhan, Mehdi,Heydari, Akbar,Faraji, Mohammad,Yamini, Yadollah
experimental part, p. 64 - 69 (2010/07/05)
Treatment of aqueous formic acid (85%) with structurally diverse amines in the presence of a catalytic amount of sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe2O3 [HAp@-γ-Fe2O3] (0.9 mol.%) as a heterogeneous, reusable and highly efficient catalyst gave the corresponding formamides in good to excellent yields at room temperature. The magnetically catalytic system was recovered by-passing time consuming filtration operation by using an external magnet device. In addition to facility, this methodology, it also enhances product purity and promises economic as well as environmental benefits.
Facile and highly efficient N-formylation of amines using a catalytic amount of iodine under solvent-free conditions
Kim, Joong-Gon,Jang, Doo Ok
experimental part, p. 2093 - 2096 (2010/10/03)
We developed a simple, practical, and catalytic method for the N-formylation of a wide variety of amines in the presence of molecular iodine as a catalyst under solvent-free conditions. This reaction is applicable to the chemoselective N-formylation of amino groups and -amino acid esters without epimerization.
2,2,2-trifluoroethyl formate: a versatile and selective reagent for the formylation of alcohols, amines, and N-hydroxylamines.
Hill, David R,Hsiao, Chi-Nung,Kurukulasuriya, Ravi,Wittenberger, Steven J
, p. 111 - 113 (2007/10/03)
[reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields.
