313697-17-5

Basic information

• Product Name: methyl 3-(phenylamino)-2-thiophenecarboxylate
• Synonyms: methyl 3-(phenylamino)-2-thiophenecarboxylate
• CAS NO: 313697-17-5
• Molecular Weight: 233.291
• Mol File: 313697-17-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 3-(phenylamino)-2-thiophenecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(phenylamino)-2-thiophenecarboxylate(313697-17-5)
• EPA Substance Registry System: methyl 3-(phenylamino)-2-thiophenecarboxylate(313697-17-5)

Safety Data

• Hazardous Substances Data: 313697-17-5(Hazardous Substances Data)

Upstream product

• 22288-78-4 Methyl 3-aminothiophene-2-carboxylate 
• 591-50-4 iodobenzene 
• 108-86-1 bromobenzene 
• 26137-08-6 methyl 3-bromothiophene-2-carboxylate 
• 62-53-3 aniline 

Relevant articles and documents

Copper- and Cobalt-Catalyzed Syntheses of Thiophene-Based Tertiary Amines

Thienylzinc halides and related compounds prepared by deprotonation followed by transmetalation were used in copper-catalyzed amination using N-benzoyloxy secondary amines. By extending the reaction to 1,5-naphthyridine, it was showed that the competitive dimer formation observed in the case of thiophenes was linked with the low stability of some thienylamines rather than homocoupling. Interestingly, thienylzinc halides and related compounds prepared by transmetalation of thienylmagnesium halides, either prepared from their bromo-precursors or generated by deprotometalation, were satisfactorily employed in cobalt-catalyzed aminations. Finally, aminothiophenes were involved in copper-catalyzed mono- and di-N-arylations, affording differently substituted di- and triphenylamines.

LIGHT-EMITTING MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC ELECTROLUMINESCENT DEVICE USING SAME, AND MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE

Disclosed are a fused compound having excellent emission wavelength control and luminous efficiency, a method for manufacturing the same, and an organic electronic device including the fused compound. Symmetric, asymmetric, and planar structures of the pr

An advantageous synthesis of new indazolone and pyrazolone derivatives

The synthesis of new indazolone and pyrazolone derivatives starting from methyl anthranilate type substrates is presented. This general approach constitutes a novel and advantageous alternative for the synthesis of the target heterocycles, which implies the use of the environmentally friendly oxidizer PIFA. The synthetic design includes the oxidation of N-arylamides by the hypervalent iodine reagent to the corresponding N-acylnitrenium ions, which can be intramolecularly trapped by an amine moiety to furnish the title compounds by formation of a new N-N single bond.