31401-23-7

Basic information

• Product Name: Benzenesulfinyl chloride, 4-methoxy-
• CAS NO: 31401-23-7
• Molecular Formula: C7H7ClO2S
• Molecular Weight: 190.65
• Mol File: 31401-23-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzenesulfinyl chloride, 4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfinyl chloride, 4-methoxy-(31401-23-7)
• EPA Substance Registry System: Benzenesulfinyl chloride, 4-methoxy-(31401-23-7)

Safety Data

• Hazardous Substances Data: 31401-23-7(Hazardous Substances Data)

Upstream product

• 100-66-3 methoxybenzene 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 118268-73-8 p-methoxybenzenesulfinic acid allyl ester 
• 1709-60-0 4-methoxybenzenesulfinic acid 
• 6462-50-6 sodium 4-methoxybenzenesulfinate 
• 696-63-9 4-Methoxybenzenethiol 

Downstream Products

• 26974-29-8 S-phenyl 4-methoxybenzenesulfinothioate 
• 314254-97-2 C₁₈H₂₂O₄S 
• 221660-80-6 Sch 57790 
• 221660-80-6 (4-Cyclohexyl-piperazin-1-yl)-[4-((R)-4-methoxy-benzenesulfinyl)-phenyl]-acetonitrile 
• 1104591-25-4 N-[(4-methoxyphenyl)sulfinyl]-2-methyl-1,4-benzoquinone imine 
• 1104591-37-8 N-[(4-methoxyphenyl)sulfinyl]-2,6-di-tert-butyl-1,4-benzoquinone imine 
• 1104591-16-3 N-[(4-methoxyphenyl)sulfinyl]-1,4-benzoquinone imine 
• 1044572-77-1 tert-butyl 4-[(4-methoxyphenyl)sulfinyl]benzoate 
• 1044572-79-3 4-[(4-methoxyphenyl)sulfinyl]benzonitrile 
• 1044572-73-7 4-iodophenyl 4'-methoxyphenyl sulfoxide 
• 398126-90-4 1-methoxy-4-{[4-(trifluoromethyl)phenyl]sulfinyl}benzene 
• 1158986-97-0 1-fluoro-4-((4-methoxyphenyl)sulfinyl)benzene 
• 97031-22-6 S-4-methoxyphenyl 4-methoxybenzenesulfinothioate 
• 92387-04-7 2-(p-methoxyphenylsulfonyl)-1-phenylpropene 

Relevant articles and documents

Regio- and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light

By visible-light photoredox catalysis with copper complexes, sulfoximidoyl chlorides add to terminal aryl alkynes to give the corresponding (E)-β-chlorovinyl sulfoximines with exclusive regio- and stereoselectivities in high yields. Two representative pro

A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides

Unprotected tertiary sulfonimidamides have been prepared in good to excellent yields in a one-pot transformation from tertiary sulfinamides through NH transfer. The reaction is mediated by commercially available (diacetoxyiodo)benzene and ammonium carbamate in methanol under convenient conditions. A wide range of functional groups are tolerated and initial results indicate that the NH transfer is stereospecific. A small molecule X-ray analysis of NH sulfonimidamide 2 a and its behavior in selected in vitro assays in comparison to the matched sulfonamide are also reported. This new reaction provides a safe, short and efficient approach to sulfonimidamides, which have been the subject of recent, growing interest in the life sciences.

Serial ligand catalysis: A highly selective allylic C-H oxidation

We are reporting a mild, chemo-, and highly regioselective Pd(II)-catalyzed allylic oxidation of α-olefins to furnish branched allylic esters that proceeds via a novel serial ligand catalysis mechanism in which two different ligands (i.e., vinyl sulfoxide 2 and BQ) interact sequentially with the metal to promote distinct steps of the catalytic cycle (i.e., C-H cleavage and π-allyl functionalization, respectively). Copyright