3141-04-6Relevant articles and documents
Enantioselective 1,3-Dipolar [6+4] Cycloaddition of Pyrylium Ions and Fulvenes towards Cyclooctanoids
McLeod, David,Cherubini-Celli, Alessio,Sivasothirajah, Nisanhi,McCulley, Christina H.,Christensen, Mette Louise,J?rgensen, Karl Anker
supporting information, p. 11417 - 11422 (2020/08/06)
Organocatalytic enantioselective 1,3-dipolar [6+4] cycloadditions of pyrylium ion intermediates with fulvenes promoted by a chiral primary amine catalyst have been developed to proceed in moderate to good yields and high enantioselectivities. The resultant chiral bicyclo[6.3.0]undecane scaffold containing a transannular bridging ether is densely functionalised providing a rigid scaffold for further manipulations. Computational studies give important insights into the role of the primary amine catalyst. Analysis of the reaction shows that the catalytic reaction proceeds in a step-wise manner and rationalises the stereochemical outcome of the reaction. Several stereoselective complexity-generating transformations, facilitated by the diverse functional groups and transannular bridge, are presented, highlighting the versatility of the core towards a number of the cyclooctanoid natural products.
Olefin high-temperature polymerization metallocene catalyst and preparation method thereof and application of olefin high-temperature polymerization metallocene catalyst in olefin polymerization
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Paragraph 0086, (2016/10/10)
The invention discloses an olefin high-temperature polymerization metallocene catalyst and a preparation method thereof and an application of the olefin high-temperature polymerization metallocene catalyst in olefin polymerization. The metallocene catalys
METALLOCENE COMPOUNDS, CATALYST COMPOSITIONS COMPRISING THE SAME, AND METHOD FOR PREPARING OLEFIN POLYMERS USING THE SAME (AS AMENDED)
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Paragraph 0082-0083, (2016/10/31)
The present invention relates to a transition metal compound that may exhibit high activity in olefin polymerization, and easily control the properties of synthesized olefin polymer such as a chemical structure, molecular weight distribution, a mechanical property, and the like, a catalyst composition comprising the same, and a method for olefin polymerization using the catalyst composition.