314294-00-3

Basic information

• Product Name: [1,1':3',1''-Terphenyl]-2'-amine, 2,2'',4,4'',6,6''-hexakis(1-methylethyl)-
• CAS NO: 314294-00-3
• Molecular Formula: C36H51N
• Molecular Weight: 497.808
• Mol File: 314294-00-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,1':3',1''-Terphenyl]-2'-amine, 2,2'',4,4'',6,6''-hexakis(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1':3',1''-Terphenyl]-2'-amine, 2,2'',4,4'',6,6''-hexakis(1-methylethyl)-(314294-00-3)
• EPA Substance Registry System: [1,1':3',1''-Terphenyl]-2'-amine, 2,2'',4,4'',6,6''-hexakis(1-methylethyl)-(314294-00-3)

Safety Data

• Hazardous Substances Data: 314294-00-3(Hazardous Substances Data)

Upstream product

• 119072-54-7 2,6-dimethylphenyl isonitrile 
• 127593-28-6 [(R)-(+)-1,1‘-binaphthalene-2,2’-diylbis(diphenylphosphane)]palladium(II)chloride 
• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 349-59-7 3,5-bis(trifluoromethyl)styrene 

Downstream Products

• 1542799-95-0 bis((2,4,6,2'',4'',6''-hexaisopropyl-1,1':3';1''-terphenyl-2')amino)tetramethyldisilazane 
• 1186534-92-8 [Fe(N(H)(C₆H₃-2,6-(C₆H₂-2,4,6-iPr₃)2)2] 

Relevant articles and documents

An Isolable Mononuclear Palladium(I) Amido Complex

Mononuclear Pd(I) species are putative intermediates in Pd-catalyzed reactions, but our knowledge about them is limited due to difficulties in accessing them. Herein, we report the isolation of a Pd(I) amido complex, [(BINAP)Pd(NHArTrip)] (BINAP = 2,2′-bis(diphenylphosphino)-1,1′-binaphthalene, ArTrip = 2,6-bis(2′,4′,6′-triisopropylphenyl)phenyl), from the reaction of (BINAP)PdCl2 with LiNHArTrip. This Pd(I) amido species has been characterized by X-ray crystallography, electron paramagnetic resonance, and multiedge Pd X-ray absorption spectroscopy. Theoretical study revealed that, while the three-electron-two-center π-interaction between Pd and N in the Pd(I) complex imposes severe Pauli repulsion in its Pd-N bond, pronounced attractive interligand dispersion force aids its stabilization. In accord with its electronic features, reactions of homolytic Pd-N bond cleavage and deprotonation of primary amines are observed on the Pd(I) amido complex.