3153-72-8Relevant articles and documents
Synthesis of biaryls by Pd-catalyzed decarboxylative homo- and heterocoupling of substituted benzoic acids
Xie, Kai,Wang, Sizhuo,Yang, Zhiyong,Liu, Jidan,Wang, Anwei,Li, Xiujian,Tan, Ze,Guo, Can-Cheng,Deng, Wei
supporting information; experimental part, p. 5787 - 5790 (2011/11/06)
By carefully choosing the right substrate ratio, catalyst combination, and base, symmetrical and unsymmetrical biaryls can be readily synthesized through the Pd-catalyzed decarboxylative homo- and heterocoupling of substituted benzoic acids. The reaction gave the desired products in 40-90% yield and is compatible with 2-nitro-, 2-methoxy-, 2-fluoro-, and 2-chloro-substituted benzoic acids. With the correct substrate ratio, catalyst combination, and base, symmetrical and unsymmetrical biaryls can be readily synthesized through the Pd-catalyzed decarboxylative homo- and heterocoupling of substituted benzoic acids.
Palladium-catalyzed cross-coupling of organolead compounds with hypervalent iodonium salts
Kang, Suk-Ku,Choi, Sang-Chul,Baik, Tae-Gon
, p. 2493 - 2499 (2007/10/03)
The palladium-catalyzed cross-coupling of hypervalent iodonium salts with organolead triacetates was achieved with Pd2(dba)3 · CHCl3 (5 mol %) in the presence of NaOMe (2 equiv) in CHCl3 at room temperature.
Nickel-Catalyzed Synthesis of Arylacetonitriles from Arylzinc Chlorides and Bromoacetonitrile
Frejd, Torbjoern,Klingstedt, Tomas
, p. 40 - 42 (2007/10/02)
Arylacetonitriles are synthesised by coupling arylzinc chlorides with bromoacetonitrile using Ni(acac)2/P(c-C6H11)(C6H5)2 as catalyst.The arylacetonitriles are reduced in situ with LiAlH4/AlCl3 to give the corresponding 2-aryl-1-aminoethanes.