31593-31-4

Basic information

• Product Name: 2-(benzylthio)-1-(4-phenylphenyl)ethanone
• Synonyms: 2-(benzylthio)-1-(4-phenylphenyl)ethanone
• CAS NO: 31593-31-4
• Molecular Weight: 318.439
• Mol File: 31593-31-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(benzylthio)-1-(4-phenylphenyl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzylthio)-1-(4-phenylphenyl)ethanone(31593-31-4)
• EPA Substance Registry System: 2-(benzylthio)-1-(4-phenylphenyl)ethanone(31593-31-4)

Safety Data

• Hazardous Substances Data: 31593-31-4(Hazardous Substances Data)

Upstream product

• 885517-60-2 2-acetyl-3,3-bis-allylsulfanyl-N-o-tolyl-acrylamide 
• 145508-26-5 2-(bis(methylthio)methylene)-3-oxo-N-(o-tolyl)butanamide 
• 875778-80-6 2-[bis(benzylthio)methylene]-3-oxo-N-o-tolylbutanamide 
• 135-73-9 2-Bromo-4'-phenylacetophenone 
• 850998-07-1 2-acetyl-3,3-bis-ethylsulfanyl-N-o-tolyl-acrylamide 

Relevant articles and documents

An efficient and odorless synthesis of thioethers using 2-[Bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as thiol equivalents

Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides 1 as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 1 commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. It is noteworthy that only a very faint odor of thiols can be perceived during both the reaction and the workup. Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 2-[bis(alkylthio)methylene] -3-oxo-N-o-tolylbutanamides commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. Copyright