31599-59-4

Basic information

• Product Name: 2-(diacetoxyiodo)toluene
• Synonyms: 2-(diacetoxyiodo)toluene
• CAS NO: 31599-59-4
• Molecular Weight: 336.126
• Mol File: 31599-59-4.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: 2-(diacetoxyiodo)toluene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(diacetoxyiodo)toluene(31599-59-4)
• EPA Substance Registry System: 2-(diacetoxyiodo)toluene(31599-59-4)

Safety Data

• Hazardous Substances Data: 31599-59-4(Hazardous Substances Data)

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 127-09-3 sodium acetate 
• 79-21-0 peracetic acid 
• 108-88-3 toluene 

Downstream Products

• 87167-83-7 2-methylphenyliodine bis(trifluoroacetate) 
• 1222532-05-9 (2,4,6-trimethylphenyl)(2'-methylphenyl)iodonium tosylate 
• 20851-07-4 2,3,5-triphenylthiophene 
• 731817-53-1 2,4-di-p-tolylselenophen 
• 51678-24-1 2,4-diphenylselenophene 
• 65398-77-8 2,4-bis(4-bromophenyl)thiophene 
• 62497-31-8 2,4-bis(4-methylphenyl)thiophene 
• 3328-86-7 2,4-diphenylthiophene 
• 842-80-8 2,4-bis(4-fluorophenyl)thiophene 

Relevant articles and documents

Conformational structure and energetics of 2- methylphenyl(2′methoxyphenyl)iodonium chloride: Evidence for solution clusters

Diaryliodonium salts allow the efficient incorporation of cyclotronproduced [18F]fluoride ions into electron-rich and electron-deficient arenes to provide potential radiotracers for molecular imaging in vivo with positron emission tomography (P

Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts

A novel approach to the preparation of imidazole-substituted cyclic iodonium salts has been developed via the oxidative cyclization of 1-phenyl-5-iodoimidazole using a cheap and available Oxone/H2SO4 oxidative system. The structure of the new polycyclic heteroarenes has been confirmed by single-crystal X-ray diffractometry, revealing the characteristic structure features for cyclic iodonium salts. The newly produced imidazole-flanked cyclic iodonium compounds were found to readily engage in a heterocyclization reaction with elemental sulfur, affording benzo[5,1-b]imidazothiazoles in good yields.

N -Heterocyclic Carbene-Catalyzed Olefination of Aldehydes with Vinyliodonium Salts to Generate α,β-Unsaturated Ketones

An organocatalyzed metal-free, direct olefination of aldehydes with vinyliodonium salts has been achieved by an N-heterocyclic carbene-promoted C-H bond activation. The reaction proceeds under very mild conditions, delivering a range of (hetero)aryl-vinyl ketones in good yields. The retention of the double bond configuration is uniformly observed, and the application of 2-methoxyphenyl auxiliary group in iodonium salts secures a complete selectivity of the vinyl transfer.