31641-96-0

Basic information

• Product Name: (1α,4α,4aβ,8bβ)-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene
• Synonyms: (1α,4α,4aβ,8bβ)-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene
• CAS NO: 31641-96-0
• Molecular Weight: 170.254
• Mol File: 31641-96-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1α,4α,4aβ,8bβ)-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene(CAS DataBase Reference)
• NIST Chemistry Reference: (1α,4α,4aβ,8bβ)-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene(31641-96-0)
• EPA Substance Registry System: (1α,4α,4aβ,8bβ)-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene(31641-96-0)

Safety Data

• Hazardous Substances Data: 31641-96-0(Hazardous Substances Data)

Upstream product

• 498-66-8 norborn-2-ene 
• 108-86-1 bromobenzene 
• 591-50-4 iodobenzene 

Relevant articles and documents

An improved synthesis of 1,4-cis,exo-hexa- or tetrahydromethano- or -ethanobiphenylene derivatives catalyzed by palladium complexes

A direct way to prepare cis,exo-hexahydromethano- or -ethanobiphenylene derivatives involving intramolecular aromatic C-H activation is reported. It consists of the palladium-catalyzed reaction of a rigid olefin with an aryl halide in dimethyl formamide i

PALLADIUM-CATALYZED C-C BOND FORMATION INVOLVING AROMATIC C-H ACTIVATION. IV. NEW SYNTHETIC APPLICATIONS OF INSERTION REACTIONS COUPLED WITH INTRAMOLECULAR AROMATIC SUBSTITUTION

Synthetic potentialites of new types of Pd-catalyzed intramolecular aromatic substitution, involving strained olefin insertion, have been explored.The reaction leading to hexahydromethanobiphenylene derivatives in their exo form appears to offer the widest synthetic applications.The use of hindered phenoxides is shown to lead to high selectivity.