31650-28-9Relevant articles and documents
Bis(2-thienyl)silanes: new, versatile precursors to arylsilanediols
Anderson, Thomas F.,Statham, Matthew A.J.,Carroll, Michael A.
, p. 3353 - 3355 (2007/10/03)
Silanediols have been shown to be effective bioisosteres for the hydrated carbonyl group. Current methods for the formation of silanediols place a number of constraints on how and where this functionality may be used. A range of arylsilanes that would allow both the formation of arylsilanediols and that are also compatible with multi-step synthetic routes, have been investigated as possible precursors to silanediols. Through this study bis(2-furyl)silanes and, in particular, bis(2-thienyl)silanes have been identified as practical precursors to arylsilanediols.
Syntheses and Electrical Properties of Organosilicon Polymers Containing Thiophene and Anthraquinone Units
Yi, Sang Ho,Ohashi, Syunsuke,Sato, Hisaya,Nomori, Hiroyuki
, p. 1244 - 1247 (2007/10/02)
Organosilicon polymers containing thiophene and anthraquinone units in the main chain were synthesized using palladium catalyst.These polymers were soluble and showed a small UV absorption change by the substituents on the silicon atom.Some of the polymers exhibit cation doping (n-doping) by the electrochemical reduction, and this doping process seemed to depend on the kinds of substituents on silicon atom.These polymers showed electrical conductivity of 3 * 10-5 S cm1- when doped with sodium naphthalenide.
