319491-92-4

Basic information

• Product Name: Spiro[1,3-dioxolane-2,2-[6]oxabicyclo[3.1.0]hexane], (+)-
• Synonyms: Spiro[1,3-dioxolane-2,2-[6]oxabicyclo[3.1.0]hexane], (+)-
• CAS NO: 319491-92-4
• Molecular Formula: C₇H₁₀O₃
• Molecular Weight: 142.15
• Mol File: 319491-92-4.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Spiro[1,3-dioxolane-2,2-[6]oxabicyclo[3.1.0]hexane], (+)-(CAS DataBase Reference)
• NIST Chemistry Reference: Spiro[1,3-dioxolane-2,2-[6]oxabicyclo[3.1.0]hexane], (+)-(319491-92-4)
• EPA Substance Registry System: Spiro[1,3-dioxolane-2,2-[6]oxabicyclo[3.1.0]hexane], (+)-(319491-92-4)

Safety Data

• Hazardous Substances Data: 319491-92-4(Hazardous Substances Data)

Upstream product

• 695-56-7 1,4-dioxaspiro[4.4]non-6-ene 
• 120-92-3 cyclopentanone 

Downstream Products

• 109459-59-8 1,4-dioxaspiro[4.4]nonan-7-one 
• 3859-41-4 1,3-cyclopentadione 
• 109459-57-6 3-hydroxy-cyclopentanone ethylene acetal 

Relevant articles and documents

Synthesis of Complex Stereoheptads en Route to Daphnane Diterpene Orthoesters

Tricyclic cores of the daphnane diterpene orthoesters (DDOs) are synthesized in 10 steps from readily available materials. Key to their assembly is the development of a stereocontrolled p-quinol functionalization sequence which enables rapid access to DDO C-ring stereopolyads from simple precursors. Problems encountered in stereo- and regioselectivity are highlighted and solved by exact changes in choreography, although it is shown that the undesired stereochemical outcomes also proceed with high selectivity.

Chiral acetals in organic synthesis: Regioselective synthesis of 2-and 3-hydroxy acetals from 2,3-olefinic acetals. Reinvestigation and further applications

Achiral as well as chiral 2,3-olefinic acetals are converted into 2- and 3- hydroxy acetals via LAH reduction of the corresponding epoxides and via bromohydrins followed by TBTH reductions respectively. Synthesis of 1,3-diones is described. Compounds from chiral systems are further utilized for asymmetric synthesis.

Synthesis and antimicrobial activity of a carbocyclic puromycin analog. 6-Dimethylamino-9-(R(2R-hydroxy-3R-(p-methoxyphenyl-L alanylamino))-cyclopentyl)purine.

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