3199-85-7

Basic information

• Product Name: 6H-Indeno[1,2-b]oxirene, 1a,6a-dihydro-6a-methyl-
• CAS NO: 3199-85-7
• Molecular Formula: C10H10O
• Mol File: 3199-85-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 6H-Indeno[1,2-b]oxirene, 1a,6a-dihydro-6a-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 6H-Indeno[1,2-b]oxirene, 1a,6a-dihydro-6a-methyl-(3199-85-7)
• EPA Substance Registry System: 6H-Indeno[1,2-b]oxirene, 1a,6a-dihydro-6a-methyl-(3199-85-7)

Safety Data

• Hazardous Substances Data: 3199-85-7(Hazardous Substances Data)

Upstream product

• 2177-47-1 2-Methylindene 

Downstream Products

• 3199-90-4 Aethyl-4-<2-hydroxy-2-methoxyindanyl>-aminobenzoat 

Relevant articles and documents

New mannose-derived ketones as organocatalysts for enantioselective dioxirane-mediated epoxidation of arylalkenes. Part 3: Chiral ketones from sugars

New d-arabino-hexopyranosid-3-uloses were synthesized by a simple method from mannopyranoside derivatives. The common skeleton possesses a tunable alkoxy group as steric sensor on carbon 2 of the sugar. The new ketones were employed in the dioxirane-mediated epoxidation of a range of trans- and trisubstituted arylalkenes giving enantiomeric excesses from low to good (30-90%). The effect of the size of the steric sensor on the enantioselectivity was also studied. The least bulky group (methoxy group) enhanced the stereoselectivity (up to 90% ee toward triphenylethylene).

Process for the ruthenium-catalysed epoxidation of olefins by means of hydrogen peroxide

The present invention relates to a process for the epoxidation of olefins using catalysts based on ruthenium complexes in the presence of hydrogen peroxide.