3200-36-0

Basic information

• Product Name: N-[[(3-Methoxyphenyl)amino]methylene]-3-methoxyaniline
• Synonyms: N,N'-Bis(3-methoxyphenyl)formamidine;N,N'-Di(3-methoxyphenyl)formamidine;N-[[(3-Methoxyphenyl)amino]methylene]-3-methoxyaniline;N1,N2-Bis(3-methoxyphenyl)formamidine
• CAS NO: 3200-36-0
• Molecular Formula: C₁₅H₁₆N₂O₂
• Molecular Weight: 256.2997
• Mol File: 3200-36-0.mol
• Article Data: 9

Chemical Properties

• Melting Point: 107-109 °C(Solv: ethanol (64-17-5))
• Boiling Point: 405.5°Cat760mmHg
• Flash Point: 199°C
• Appearance: /
• Density: 1.07g/cm³
• PKA: 6.67±0.50(Predicted)
• CAS DataBase Reference: N-[[(3-Methoxyphenyl)amino]methylene]-3-methoxyaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-[[(3-Methoxyphenyl)amino]methylene]-3-methoxyaniline(3200-36-0)
• EPA Substance Registry System: N-[[(3-Methoxyphenyl)amino]methylene]-3-methoxyaniline(3200-36-0)

Safety Data

• Hazardous Substances Data: 3200-36-0(Hazardous Substances Data)

Upstream product

• 16460-28-9 N,N'-bis(3-methoxyphenyl)urea 
• 536-90-3 m-Anisidine 
• 122-51-0 orthoformic acid triethyl ester 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 49754-71-4 1-(3-Methoxy-phenyl)-1-{[(Z)-3-methoxy-phenylimino]-methyl}-3,3-dimethyl-urea 
• 49754-87-2 1-(3-Methoxy-phenyl)-1-{[(E)-3-methoxy-phenylimino]-methyl}-3-methyl-urea 

Relevant articles and documents

Synthetic Applications of a New Magnetic Mesoporous Nanocomposite Catalyst Fe3O4@MCM-41@NH-SO3H

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An efficient method for the synthesis of formamidine and formamide derivatives promoted by sulfonated rice husk ash (RHA-SO3H)

A mild, simple and efficient method has been developed for the promotion of the preparation of N,N′-diphenylformamidines from various aromatic amines and ethyl orthoformate using sulfonated rice husk ash (RHA-SO3H) solid acid catalyst. This reagent has also been used for the N-formylation of a variety of amines using formic acid under solvent-free conditions. The procedures gave the products in very short reaction times and good-to-high yields. Also this catalyst can be reused for five times without loss of its catalytic activity.

Pushing back the limits of hydrosilylation: Unprecedented catalytic reduction of organic ureas to formamidines

Pushing back the limits: A novel catalytic transformation has been designed to prepare formamidine derivatives by reduction of substituted ureas with hydrosilanes. Simple iron catalysts based on commercially available iron salts and phosphine ligands prov