320410-60-4

Basic information

• Product Name: (1R,2R,3S,4S)-5-iodocyclohex-5-ene-1,2,3,4-tetraol
• Synonyms: (1R,2R,3S,4S)-5-iodocyclohex-5-ene-1,2,3,4-tetraol
• CAS NO: 320410-60-4
• Molecular Weight: 272.04
• Mol File: 320410-60-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1R,2R,3S,4S)-5-iodocyclohex-5-ene-1,2,3,4-tetraol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,3S,4S)-5-iodocyclohex-5-ene-1,2,3,4-tetraol(320410-60-4)
• EPA Substance Registry System: (1R,2R,3S,4S)-5-iodocyclohex-5-ene-1,2,3,4-tetraol(320410-60-4)

Safety Data

• Hazardous Substances Data: 320410-60-4(Hazardous Substances Data)

Upstream product

• 138769-92-3 cis-(1S,2S)-1,2-dihydroxy-3-iodocyclohexa-3,5-diene 
• 165611-18-7 (3aS,4R,5R,7aS)-7-iodo-2,2-dimethyl-3a,4,5,7a-tetrahydro-1,3-benzodioxole-4,5-diol 
• 154784-39-1 (3aS,7aS)-4-iodo-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole 

Downstream Products

• 86117-81-9 (1S,2R,3R,4S,5S)-5-(hydroxymethyl)cyclohexane-1,2,3,4-tetraol 
• 856890-18-1 (1R,2S,5R,6S)-2,5,6-tri(acetyloxy)-4-iodo-3-cyclohexenyl acetate 
• 856890-19-2 methyl (3S,4R,5R,6S)-3,4,5,6-tetra(acetyloxy)-1-cyclohexene-1-carboxylate 
• 858037-17-9 methyl (1R,2S,3R,4R,5S)-2,3,4,5-tetra(acetyloxy)cyclohexane-1-carboxylate 
• 320410-71-7 (1R,2R)-4-iodo-3,5-cyclohexadiene-1,2-diol 
• 900792-05-4 (1S,2R,5S,6S)-6-(acetyloxy)-2,5-dibromo-3-iodo-3-cyclohexenyl acetate 

Relevant articles and documents

Chemoenzymatic synthesis of carbasugars (+)-pericosines A-C from diverse aromatic cis-dihydrodiol precursors

cis-Dihydrocatechols, derived from biological cis-dihydroxylation of methyl benzoate, iodobenzene and benzonitrile, using the microorganism Pseudomonas putida UV4, were converted into pericosines A, C, and B, respectively. This approach constitutes the shortest syntheses, to date, of these important natural products with densely packed functionalities.

Chemoenzymatic synthesis of carbasugars from iodobenzene

The versatile enantiopure cis-dihydrodiol metabolite 1, formed by bacterial metabolism of iodobenzene, has been used for the synthesis of the pyranose carbasugars (pseudosugars) carba-β-D-altropyranose 2, carba-α-L- galactopyranose 3, carba-β-D-idopyranos