32133-82-7 Usage
Description
BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR is a complex organic compound with a unique chemical structure. It is characterized by its ability to act as a dehydrating and oxidizing agent, making it a valuable component in various chemical reactions and processes.
Uses
Used in Chemical Synthesis:
BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR is used as a dehydrating and oxidizing agent in the field of chemical synthesis. Its application is crucial for facilitating specific chemical reactions and enhancing the overall efficiency of the synthesis process.
Used in Research and Development:
In the research and development industry, BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR is employed as a versatile agent for exploring new chemical reactions and understanding the underlying mechanisms. Its unique properties allow researchers to investigate a wide range of chemical phenomena and develop innovative solutions in various fields.
For more information on the chemistry and references related to BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR, one can refer to Aldrichimica Acta, a reputable source for chemical information and research.
Check Digit Verification of cas no
The CAS Registry Mumber 32133-82-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,1,3 and 3 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 32133-82:
(7*3)+(6*2)+(5*1)+(4*3)+(3*3)+(2*8)+(1*2)=77
77 % 10 = 7
So 32133-82-7 is a valid CAS Registry Number.
InChI:InChI=1/C30H20F12O2S/c31-27(32,33)25(28(34,35)36,21-13-5-1-6-14-21)43-45(23-17-9-3-10-18-23,24-19-11-4-12-20-24)44-26(29(37,38)39,30(40,41)42)22-15-7-2-8-16-22/h1-20H
32133-82-7Relevant articles and documents
A Unified Approach for the Assembly of Atisine- and Hetidine-type Diterpenoid Alkaloids: Total Syntheses of Azitine and the Proposed Structure of Navirine C
Liu, Jie,Ma, Dawei
, p. 6676 - 6680 (2018)
A tetracyclic dinitrile was synthesized in twelve steps from cyclohex-2-en-1-one by using a chelation-triggered conjugate addition to a γ-hydroxy-substituted α,β-unsaturated nitrile and an oxidative dearomatization/Diels–Alder cycloaddition cascade as the key steps. The first total synthesis of azitine (in 17 steps) was achieved through a simple reductive cyclization of this intermediate and subsequent transformations while the total synthesis of the proposed structure of navirine C (in 19 steps) was accomplished by a hydrogen-atom-transfer reaction of the tetracyclic dinitrile, Pd/C-catalyzed reductive cyclization, and subsequent functional group manipulation.
