32135-09-4

Basic information

• Product Name: bis(benzyloxy)diethylsilane
• Synonyms: bis(benzyloxy)diethylsilane
• CAS NO: 32135-09-4
• Molecular Weight: 300.473
• Mol File: 32135-09-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: bis(benzyloxy)diethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: bis(benzyloxy)diethylsilane(32135-09-4)
• EPA Substance Registry System: bis(benzyloxy)diethylsilane(32135-09-4)

Safety Data

• Hazardous Substances Data: 32135-09-4(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 542-91-6 H₂SiEt₂ 
• 100-52-7 benzaldehyde 
• 86934-33-0 Diethyl-bis-(1-methoxy-2-methyl-propenyloxy)-silane 

Relevant articles and documents

Use of Silylated Formiates as Hydrosilane Equivalents

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes

An O-Si bond construction protocol employing abundantly available and inexpensive NaOH as the catalyst is described. The method enables the cross-dehydrogenative coupling of an alcohol and hydrosilane to directly generate the corresponding silyl ether under mild conditions and without the production of stoichiometric salt byproducts. The scope of both coupling partners is excellent, positioning the method for use in complex molecule and materials science applications. A novel Si-based cross-coupling reagent is also reported.

O-SILYLATED KETENE ACETAL CHEMISTRY; DIVINYLOXYSILANE DERIVATIVES AS NOVEL AND USEFUL BIFUNCTIONAL PROTECTING AGENTS FOR H-ACIDIC MATERIALS

Novel reagents, bis(1-methoxy-2-methyl-1-propenyloxy)silanes (2a-d) have been shown to be very useful bifunctional protecting agents for various types of H-acidic materials, such as diols, dithiols, diacids and their combined materials.The reaction proceeds rapidly under mild conditions to give the corresponding silylene derivatives in almost quantitative yields.