321725-00-2Relevant articles and documents
Picosecond photoreduction of inducible nitric oxide synthase by rhenium(I)-diimine wires
Belliston-Bittner, Wendy,Dunn, Alexander R.,Le Nguyen, Yen Hoang,Stuehr, Dennis J.,Winkler, Jay R.,Gray, Harry B.
, p. 15907 - 15915 (2007/10/03)
In a continuing effort to unravel mechanistic questions associated with metalloenzymes, we are developing methods for rapid delivery of electrons to deeply buried active sites. Herein, we report picosecond reduction of the heme active site of inducible ni