321903-29-1Relevant articles and documents
Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates
Tang, Shi,Takeda, Masahide,Nakao, Yoshiaki,Hiyama, Tamejiro
supporting information; experimental part, p. 307 - 309 (2011/02/24)
Using highly stable, readily accessible, and recyclable 2-(2-hydroxyprop-2-yl)cyclohexyl-substituted arylsilanes activated by a mild carbonate base, nickel-catalysed silicon-based aryl-aryl cross-coupling reaction proceeds for the first time with inexpensive aryl chlorides and tosylates in a highly chemoselective manner.
Copper-free palladium-catalyzed Sonogashira and Hiyama cross-couplings using aryl imidazol-1-ylsulfonates
Shirbin, Steven J.,Boughton, Berin A.,Zammit, Steven C.,Zanatta, Shannon D.,Marcuccio, Sebastian M.,Hutton, Craig A.,Williams, Spencer J.
experimental part, p. 2971 - 2974 (2010/06/21)
Aryl imidazylates are effective electrophilic partners in copper-free palladium-catalyzed Hiyama and Sonogashira cross-coupling reactions. The Sonogashira cross-coupling of estron-3-yl imidazylate afforded the corresponding phenylacetylene derivative in e
Rhodium-catalyzed hydroarylation and hydroalkenylation of alkynes using organo [2-(hydroxymethyl)phenyl]dimethylsilanes
Nakao, Yoshiaki,Takeda, Masahide,Chen, Jinshui,Hiyama, Tamejiro
, p. 774 - 776 (2008/09/21)
The title reaction was found to proceed in the presence of a rhodium/1,2-bis(diphenylphosphino)benzene catalyst. Variously substituted arylethenes and 1,3-dienes were obtained in good yields. Georg Thieme Verlag Stuttgart.