32259-70-4Relevant articles and documents
Spectroscopic determination of pressure-induced shifts in inclusion complexation equilibria
Evans, Christine E.
, p. 2136 - 2142 (1997)
The effect of modest hydrostatic pressure (c ranging from clearly pressure dependent (-14%) to pressure independent over 338 bar. Additional solvation perturbations are observed in the pressure dependence of the quantum efficiency for both complexes (-7.3% and -9.4%). Thus, pressure-induced perturbation in the fluorescence properties of the complex need not be accompanied by simultaneous changes in the complexation equilibrium. Finally, these pressure-induced changes in complexation selectivity are important for all measurements conducted under variable pressure conditions, including liquid chromatography and process monitoring.
