3241-00-7

Basic information

• Product Name: AKOS B023258
• Synonyms: AKOS B023258;ART-CHEM-BB B023258;AURORA KA-7730;CHEMBRDG-BB 5534416;(4-METHOXYBENZYL)(2-PHENYLETHYL)AMINE;(4-METHOXY-BENZYL)-PHENETHYL-AMINE;AKOS JY2055877;N-(4-METHOXYBENZYL)-N-(2-PHENYLETHYL)AMINE
• CAS NO: 3241-00-7
• Molecular Formula: C₁₆H₁₉NO
• Molecular Weight: 241.33
• Mol File: 3241-00-7.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 369.3°C at 760 mmHg
• Flash Point: 154.5°C
• Appearance: /
• Density: 1.038g/cm³
• Vapor Pressure: 1.2E-05mmHg at 25°C
• Refractive Index: 1.56
• CAS DataBase Reference: AKOS B023258(CAS DataBase Reference)
• NIST Chemistry Reference: AKOS B023258(3241-00-7)
• EPA Substance Registry System: AKOS B023258(3241-00-7)

Safety Data

• Hazardous Substances Data: 3241-00-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H19NO/c1-18-16-9-7-15(8-10-16)13-17-12-11-14-5-3-2-4-6-14/h2-10,17H,11-13H2,1H3

Upstream product

• 100-42-5 styrene 
• 2393-23-9 4-methoxy-benzylamine 
• 104-21-2 p-methoxybenzyl acetate 
• 64-04-0 phenethylamine 
• 140-29-4 phenylacetonitrile 
• 171414-16-7 N-(4-methoxybenzyl)-2-nitro-N-(prop-2-yn-1-yl)benzenesulfonamide 
• 123-11-5 4-methoxy-benzaldehyde 
• 105-13-5 4-Methoxybenzyl alcohol 
• 60-12-8 2-phenylethanol 
• 3240-96-8 (4-methoxy-benzylidene)-phenethyl-amine 

Downstream Products

• 141839-23-8 N-(p-methoxybenzyl)-N-phenethylphenethylamine 
• 104178-96-3 N-propyl-2-phenylethylamine hydrochloride 
• 61185-89-5 ethyl-phenethyl-amine; hydrochloride 
• 99858-44-3 N-phenethylprop-2-en-1-aminium hydrochloride 
• 4104-43-2 methylphenethylamine hydrochloride 
• 302910-90-3 (4-methoxy-benzyl)-methyl-phenethyl-amine 

Relevant articles and documents

Aluminum Metal-Organic Framework-Ligated Single-Site Nickel(II)-Hydride for Heterogeneous Chemoselective Catalysis

The development of chemoselective and heterogeneous earth-abundant metal catalysts is essential for environmentally friendly chemical synthesis. We report a highly efficient, chemoselective, and reusable single-site nickel(II) hydride catalyst based on robust and porous aluminum metal-organic frameworks (MOFs) (DUT-5) for hydrogenation of nitro and nitrile compounds to the corresponding amines and hydrogenolysis of aryl ethers under mild conditions. The nickel-hydride catalyst was prepared by the metalation of aluminum hydroxide secondary building units (SBUs) of DUT-5 having the formula of Al(μ2-OH)(bpdc) (bpdc = 4,4′-biphenyldicarboxylate) with NiBr2 followed by a reaction with NaEt3BH. DUT-5-NiH has a broad substrate scope with excellent functional group tolerance in the hydrogenation of aromatic and aliphatic nitro and nitrile compounds under 1 bar H2 and could be recycled and reused at least 10 times. By changing the reaction conditions of the hydrogenation of nitriles, symmetric or unsymmetric secondary amines were also afforded selectively. The experimental and computational studies suggested reversible nitrile coordination to nickel followed by 1,2-insertion of coordinated nitrile into the nickel-hydride bond occurring in the turnover-limiting step. In addition, DUT-5-NiH is also an active catalyst for chemoselective hydrogenolysis of carbon-oxygen bonds in aryl ethers to afford hydrocarbons under atmospheric hydrogen in the absence of any base, which is important for the generation of fuels from biomass. This work highlights the potential of MOF-based single-site earth-abundant metal catalysts for practical and eco-friendly production of chemical feedstocks and biofuels.

Synthesis, spectral, structural and computational studies on NiS4 and NiS2NP chromophores: Anagostic and C-H?π (chelate) interactions in [Ni(dtc)(PPh3)(NCS)] (dtc = N-(2-phenylethyl)-N-(4-methoxybenzyl)- dithiocarbamate an

Bis(N-(2-phenylethyl)-N-substituted benzyldithiocarbamato-S,S′)nickel(II) (1-6) and (N-(2-phenylethyl)-N-substituted benzyldithiocarbamato-S,S′)(thiocyanato-N) (triphenylphosphine)nickel(II) (7-12) [substituted benzyl = 2HO-C6H4-CHs

One-pot synthesis of imines and secondary amines by Pd-catalyzed coupling of benzyl alcohols and primary amines

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