324745-57-5

Basic information

• Product Name: η6-(1-phenyl-4-methoxybenzene)tricarbonylchromium(0)
• CAS NO: 324745-57-5
• Molecular Weight: 320.265
• Mol File: 324745-57-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: η6-(1-phenyl-4-methoxybenzene)tricarbonylchromium(0)(CAS DataBase Reference)
• NIST Chemistry Reference: η6-(1-phenyl-4-methoxybenzene)tricarbonylchromium(0)(324745-57-5)
• EPA Substance Registry System: η6-(1-phenyl-4-methoxybenzene)tricarbonylchromium(0)(324745-57-5)

Safety Data

• Hazardous Substances Data: 324745-57-5(Hazardous Substances Data)

Upstream product

• 613-37-6 4-methoxylbiphenyl 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 56213-59-3 η6-(4-methoxyfluorobenzene)tricarbonylchromium(0) 
• 934-56-5 trimethyl(phenyl)stannane 
• 98-80-6 phenylboronic acid 
• 12082-05-2 (η6-fluorobenzene)tricarbonylchromium 
• 5720-07-0 4-methoxyphenylboronic acid 

Relevant articles and documents

Palladium catalysed cross-coupling of (fluoroarene)tricarbonyl-chromium(o) complexes

(Fluoroarene)tricarbonylchromium(o) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group. The Royal Society of Chemistry 2000.