32507-39-4

Basic information

• Product Name: Benzene, 1-(1E)-1,3-butadienyl-4-methoxy-
• CAS NO: 32507-39-4
• Molecular Formula: C11H12O
• Molecular Weight: 160.216
• Mol File: 32507-39-4.mol
• Article Data: 51

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1E)-1,3-butadienyl-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1E)-1,3-butadienyl-4-methoxy-(32507-39-4)
• EPA Substance Registry System: Benzene, 1-(1E)-1,3-butadienyl-4-methoxy-(32507-39-4)

Safety Data

• Hazardous Substances Data: 32507-39-4(Hazardous Substances Data)

Upstream product

• 2622-05-1 allylmagnesium bromide 
• 123-11-5 4-methoxy-benzaldehyde 
• 30448-78-3 p-methoxyphenylbutadiene 
• 156701-45-0 2-(prop-2-enylsulfonyl)benzothiazole 
• 627-15-6 1,3-dibromopropene 
• 939025-10-2 C₁₃H₁₃F₃O₃ 
• 1186-52-3 tetradeuterioacetic acid 
• 134747-45-8 4-(4-methoxyphenyl)-3-buten-2-ol 
• 51230-91-2 2-(4-methoxyphenyl)-4-pentenoic acid 
• 109-72-8 n-butyllithium 
• 1963-36-6 4-methoxycinnamaldehyde 
• 72033-84-2 (1E,3Z)-1,4-bis(4-methoxyphenyl)buta-1,3-diene 
• 1530-38-7 ((4-methoxyphenyl)methyl)triphenylphosphonium bromide 
• 5392-12-1 2-methoxy-1-naphthaldehyde 

Downstream Products

• 33356-91-1 6-(4-methoxy-phenyl)-2-p-tolyl-3,6-dihydro-2H-[1,2]oxazine 
• 579-10-2 N-acetyl-N-methylaniline 

Relevant articles and documents

Ni-Catalyzed Regioselective Hydroarylation of 1-Aryl-1,3-Butadienes with Aryl Halides

An efficient nickel-catalyzed regioselective hydroarylation of 1,3-dienes with aryl halides and a silane has been developed, affording a range of allylic arenes in good to excellent yields under mild conditions. This method exhibits broad substrate scope,

Nickel-Catalyzed Carboxylation of Conjugated Dienes with Carbon Dioxide and DIBAL-H for the Synthesis of β,γ-Unsaturated Carboxylic Acids

Conjugated dienes underwent Ni-catalyst-promoted 1,2-hydrocarboxylation in a 1:1 ratio with carbon dioxide under atmospheric pressure in the presence of diisobutylaluminum hydride (DIBAL-H) to give the corresponding β,γ-unsaturated carboxylic acids, without dimerization or oligomerization of the conjugated diene.

Cu-Catalyzed highly regioselective 1,2-hydrocarboxylation of 1,3-dienes with CO2

A practical copper-catalyzed highly regioselective 1,2-hydrocarboxylation of terminal 1,3-diene with carbon dioxide has been developed. Under mild reaction conditions, this chemistry afforded 2-benzyl-β,γ-unsaturated acid derivatives as products, which are a kind of important unit for bio-active molecules and versatile precursors for organic synthesis, with good functional group tolerance. The key intermediate in this transformation is illustrated by control experiments.