32588-84-4

Basic information

• Product Name: Benzene, 1-methoxy-4-nonyl-
• CAS NO: 32588-84-4
• Molecular Formula: C16H26O
• Molecular Weight: 234.382
• Mol File: 32588-84-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-nonyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-nonyl-(32588-84-4)
• EPA Substance Registry System: Benzene, 1-methoxy-4-nonyl-(32588-84-4)

Safety Data

• Hazardous Substances Data: 32588-84-4(Hazardous Substances Data)

Upstream product

• 80504-86-5 1-(4-Methoxyphenyl)-1,3-nonadiene 
• 7647-01-0 hydrogenchloride 
• 52754-68-4 1-(4-methoxy-phenyl)-nonan-1-one 
• 111-25-1 1-bromo-hexane 
• 374754-93-5 (9-BBN)(CH₂)3(p-anisyl) 
• 3391-86-4 1-octen-3-ol 
• 104-40-5 4-Nonylphenol 
• 74-88-4 methyl iodide 
• 123-11-5 4-methoxy-benzaldehyde 
• 140-67-0 Estragole 
• 738607-47-1 3-(4-methoxyphenyl)propyl phenyl sulfoxide 
• 3761-92-0 n-hexylmagnesium bromide 
• 115878-50-7 1-chloro-3-(4-methoxyphenyl)propyl phenyl sulfoxide 
• 4282-40-0 1-Iodoheptane 

Downstream Products

• 104-40-5 4-Nonylphenol 

Relevant articles and documents

Nickel-Catalyzed C(sp3)-C(sp3) Cross-Electrophile Coupling of in Situ Generated NHP Esters with Unactivated Alkyl Bromides

The formation of C(sp3)-C(sp3) bonds by cross-coupling remains a challenge in synthesis. Here, we demonstrate a two-step, one-pot protocol for the in situ generation of N-hydroxyphthalimide esters and their nickel-catalyzed cross-electrophile coupling with unactivated alkyl bromides for the construction of 1°/1 ° C(sp3)-C(sp3) bonds. The conditions tolerate an array of functional groups, and mechanistic studies indicate that both substrates are converted to alkyl radicals during the reaction.

Suzuki-Miyaura cross-coupling of aryl and alkyl halides using palladium/imidazolium salt protocols

A simple new protocol for the high yielding Suzuki-Miyaura cross-couplings of aryl chlorides with aryl boronic acids using a palladium/imidazolium salt catalytic system is presented. The first examples of a palladium/imidazolium salt protocol for sp3-sp3 Suzuki-Miyaura couplings of alkyl halides are also disclosed.

Mechanism of the Solution-Phase Reaction of Alkyl Sulfides Atomic Hydrogen. Reduction via a 9-S-3 Radical Intermediate

The low selectivity of benzyl alkyl sulfide fragmentation subsequent to its reaction with atomic hydrogen is indicative of a reaction that proceeds via an early transition state. The competitive reduction of a series of substituted-benzyl alkyl sulfides was insensitive to the substituent on the aromatic ring (ρ = -0.13, r = 0.99). The relative rates of fragmentation of a series of the substituted-benzyl alkyl sulfides gave a V-shaped Hammett plot. Both electron-donating and electron-withdrawing groups destabilized the transition state (ρ = +0.99, r = 0.999; ρ = -0.82, r = 0.992). Since the relative rates of disappearance of the alkyl benzyl sulfides are not substituent dependent, but the relative rates of fragmentation are, a 9-S-3 intermediate is preferred as the structure leading to products.