32636-65-0Relevant articles and documents
Palladium/Xiao-Phos-Catalyzed Kinetic Resolution of sec-Phosphine Oxides by P-Benzylation
Dai, Qiang,Liu, Lu,Zhang, Junliang
supporting information, p. 27247 - 27252 (2021/11/17)
P-stereogenic tert- and sec-phosphines have wide applications in asymmetric catalysis, materials, and pharmaceutical chemistry, however, their practical synthesis still constitutes a significant challenge. Herein, a successful kinetic resolution of rac-se
Synthesis of diarylmethanes through palladium-catalyzed coupling of benzylic phosphates with arylsilanes
Zhang, Pengbo,Xu, Jian,Gao, Yuzhen,Li, Xueqin,Tang, Guo,Zhao, Yufen
, p. 2928 - 2932 (2015/01/16)
An efficient approach to the benzylation of arenes has been developed. The reactions described provide straightforward access to diarylmethanes through Pd-catalyzed coupling of benzylic phosphates with arylsilanes in good to excellent yields. The reaction tolerates a wide range of functionalities such as halide, alkoxyl, and nitro groups.
Direct Esterification of Phosphates with Various Halides and its Application to Synthesis of cAMP Alkyl Triesters
Furuta, Toshiaki,Torigai, Hiromi,Osawa, Tomoko,Iwamura, Michiko
, p. 3139 - 3142 (2007/10/02)
Esterification of phosphates with various halides, including acid chlorides, phosphoryl trichloride and chloride, was achieved in 57-99percent isolated yield using silver(I) oxide.The reaction was successfully applied to the preparation of phosphate triesters sensitive to acids and bases. cAMP benzyl esters were also prepared by this method.
