3271-80-5Relevant articles and documents
A PdII Carbene Complex with Anthracene Side-Arms for π-Stacking on Reduced Graphene Oxide (rGO): Activity towards Undirected C–H Oxygenation of Arenes
Majeed, Maitham H.,Shayesteh, Payam,Persson, Axel R.,Wallenberg, L. Reine,Schnadt, Joachim,Wendt, Ola F.
supporting information, p. 4742 - 4746 (2018/11/27)
An N-heterocyclic carbene palladium(II) complex containing two anthracene side arms was immobilized on the surface of reduced graphene oxide (rGO) by π-stacking. The activity of the homogeneous analogue and the supported complex in undirected C–H acetoxylation reaction of arenes was studied. The results show that the catalytic efficiency in acetoxylation of benzene is improved in the immobilized materials compared to the homogeneous analogue. According to XPS analysis, the immobilized catalyst maintains the original oxidation state of PdII after the catalytic reaction.
Oxygenation of biphenyl by the reagent system Fe(MeCN)6(2+)-H2O2-Ac2O: an implication to the mechanism in mammalian metabolism.
Kotani,Midorikawa,Tanaka,Tobinaga
, p. 916 - 919 (2007/10/02)
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Metal Ion Oxidation. XI. Oxidation of Aromatic Hydroarbons and Arylacetic Acids by Heteropoly Anions Containing Ni(IV), Mn(IV) and Co(III) Ions as Central Atoms
Joensson, Lennart
, p. 761 - 768 (2007/10/02)
Heteropoly ions containing Ni(IV) and Mn(IV) as central atoms have been shown to oxidize aromatic hydrocarbons and arylacetic acids in acetic acid and acetic acid-water, yielding acetates and alcohols.The product patternof these reactions supports an outer-sphere electron transfer mechanism.Substituted arylacetic acids are decarboxylated when treated with 12-tungstocobalt(III)ate ion and 9-molybdonickel(IV)ate ion.These decarboxylation reactions are proposed to be outer-sphere electron transfer processes.