32742-24-8

Basic information

• Product Name: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside
• CAS NO: 32742-24-8
• Molecular Weight: 458.85
• Mol File: 32742-24-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside(32742-24-8)
• EPA Substance Registry System: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside(32742-24-8)

Safety Data

• Hazardous Substances Data: 32742-24-8(Hazardous Substances Data)

Upstream product

• 95-57-8 2-monochlorophenol 
• 439-03-2 2,3,4,6-tetra-O-acetyl-1-fluoro-α-D-glucopyranose 

Relevant articles and documents

Novel Synthesis of Aryl 2,3,4,6-Tetra-O-acetyl-D-glucopyranosides

The glucosidation of phenols with 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl fluoride in the presence of BF3*OEt2 to give, predominantly, α-anomers has been studied.In the presence of an amine base, 1,1,3,3-tetramethylguanidine, however, enhanced β-selectivity was achieved.The former reaction provides a novel and useful synthesis of aryl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside whilst the latter is effective for the glycosidation of relatively hindered phenols.