328379-54-0Relevant articles and documents
C6F5XeY Molecules (Y = F and Cl): New synthetic approaches. first structural proof of the organoxenon halide molecule C 6F5XeF
Bilir, Vural,Frohn, Hermann-Josef
, p. 505 - 512 (2013/09/23)
The arylxenonium salt [C6F5Xe][BF4] reacts with different sources of nucleophiles, Y (naked fluoride, [N(CH 3)4]F, the silanes, (CH3)3SiCl and (C2H5)3SiH, and the cadmiumorganyl, Cd(C 6F5)2), in coordinating solvents (C 2H5CN, CH3CN, CD3CN). While the products C6F5XeF, C6F5XeCl, and (C6F5)2Xe are well defined molecules, in reactions with (C2H5)3SiH only decomposition products presumably derived from 6F5XeH6F5XeC2H56F5XeF are discussed.
C6F5XeF, a key substrate in xenon-carbon chemistry: Synthesis of symmetric and asymmetric pentafluorophenylxenon(II) derivatives
Frohn, Hermann-Josef,Thei, Michael
, p. 4591 - 4593 (2007/10/03)
The "naked" fluoride [NMe4]F in CH2Cl2 converts the salt-like compound [C6F5Xe][AsF6] into the asymmetric, hypervalent molecule 1 in 70%, yield. As a result of its high fluoride-donating ability and its permanent dipole moment, 1 reacts in good yields with Cd(C6F5)2 to form Xe(C6F5)2 (2) and with Me3SiCN to form C6F5XeCN (3).