32884-97-2

Basic information

• Product Name: diethyl 2,3-dimethylsuccinate
• Synonyms: diethyl 2,3-dimethylsuccinate
• CAS NO: 32884-97-2
• Molecular Weight: 202.251
• Mol File: 32884-97-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: diethyl 2,3-dimethylsuccinate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2,3-dimethylsuccinate(32884-97-2)
• EPA Substance Registry System: diethyl 2,3-dimethylsuccinate(32884-97-2)

Safety Data

• Hazardous Substances Data: 32884-97-2(Hazardous Substances Data)

Upstream product

• 530-48-3 1,1-Diphenylethylene 
• 535-11-5 Ethyl 2-bromopropionate 
• 10170-69-1 dimanganese decacarbonyl 
• 74-88-4 methyl iodide 

Relevant articles and documents

Cooperative Ligand-Promoted P(III)-Directed Ruthenium-Catalyzed Remote Meta-C-H Alkylation of Tertiary Phosphines

Herein, we disclose a ruthenium-catalyzed meta-selective C-H activation of phosphines by using intrinsic P(III) as a directing group. 2,2,6,6-Tetramethylheptane-3,5-dione acts as the ligand and exhibits an excellent performance in boosting the meta-alkylation. The protocol allows an efficient and straightforward synthesis of meta-alkylated tertiary phosphines. Several meta-alkylated phosphines were evaluated for Pd-catalyzed Suzuki coupling and found to be superior to commercially available ortho-substituted phosphines. The practicability of this methodology is further demonstrated by the synthesis of difunctionalized phosphines.

ISOLATION AND REACTIONS OF THE LITHIUM DI-ENOLATE OF DIETHYL SUCCINATE

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