33032-80-3

Basic information

• Product Name: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
• CAS NO: 33032-80-3
• Molecular Weight: 458.85
• Mol File: 33032-80-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(33032-80-3)
• EPA Substance Registry System: o-Chlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(33032-80-3)

Safety Data

• Hazardous Substances Data: 33032-80-3(Hazardous Substances Data)

Upstream product

• 95-57-8 2-monochlorophenol 
• 439-03-2 2,3,4,6-tetra-O-acetyl-1-fluoro-α-D-glucopyranose 
• 604-69-3 β-D-glucose pentaacetate 

Downstream Products

• 7234-33-5 (2-chloro-phenyl)-β-D-glucopyranoside 

Relevant articles and documents

Novel Synthesis of Aryl 2,3,4,6-Tetra-O-acetyl-D-glucopyranosides

The glucosidation of phenols with 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl fluoride in the presence of BF3*OEt2 to give, predominantly, α-anomers has been studied.In the presence of an amine base, 1,1,3,3-tetramethylguanidine, however, enhanced β-selectivity was achieved.The former reaction provides a novel and useful synthesis of aryl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside whilst the latter is effective for the glycosidation of relatively hindered phenols.