330457-42-6

Basic information

• Product Name: 11-BROMOUNDECYLDIMETHYLCHLOROSILANE
• Synonyms: (11-Bromoundecyl)(chloro)dimethylsilane;(11-Bromundecyl)(chlor)dimethylsilan
• CAS NO: 330457-42-6
• Molecular Formula: C13H28BrClSi
• Molecular Weight: 327.8
• Mol File: 330457-42-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 170°C/1mmHg
• Flash Point: 157.318 °C
• Appearance: /
• Density: 1.03
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.463
• CAS DataBase Reference: 11-BROMOUNDECYLDIMETHYLCHLOROSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: 11-BROMOUNDECYLDIMETHYLCHLOROSILANE(330457-42-6)
• EPA Substance Registry System: 11-BROMOUNDECYLDIMETHYLCHLOROSILANE(330457-42-6)

Safety Data

• TSCA: No
• Hazardous Substances Data: 330457-42-6(Hazardous Substances Data)

Usage

General Description

11-BROMOUNDECYLDIMETHYLCHLOROSILANE is an organosilicon compound with the molecular formula C13H29BrClSi. It is a clear, colorless liquid that is primarily used as a chemical intermediate in the production of other organosilicon compounds. This chemical is commonly employed as a surface modifier and in the synthesis of specialty polymers and materials. Its chemical structure includes a silicon atom bonded to a bromine atom, a chlorine atom, and two methyl groups, as well as an 11-carbon alkyl chain. 11-BROMOUNDECYLDIMETHYLCHLOROSILANE is typically handled and stored under controlled conditions due to its flammability and potential reactivity with water and air.

InChI:InChI=1/C13H28BrClSi/c1-16(2,15)13-11-9-7-5-3-4-6-8-10-12-14/h3-13H2,1-2H3

Upstream product

• 1066-35-9 dimethylmonochlorosilane 
• 7766-50-9 1-undecen-11-ylbromide 

Relevant articles and documents

Branching the electron-reservoir complex [Fe(η5-C 5H5)(η6-C6Me6)] [PF6] onto large dendrimers: "click", amide, and ionic bonds

Several strategies have been used to functionalize 1,3,5-trisubstituted arene-cored dendrimers with the organometallic electron-reservoir moiety [Fe(η5-C5H5)(η6-C 6Me6)]+, 1, to provide dendritic multielectron reservoirs. They all start from the carboxylic acid [Fe(η5-C 5H4COOH)(η6-C6Me 6)][PF6], 2, or its acyl chloride derivative [Fe(η5-C5H4COCl)(η6-C 6Me6)][PF6], 3. For this purpose, a series of new polyamine dendrimers from G0 to G2 with 1→ 3 C connectivity of the branching to the core have been synthesized. Amide, "click" and ionic ammonium carboxylate linkage successfully provided G0, G1, and G2 metallodendrimers with 9, 27, and 81 cationic terminal organoiron groups respectively. Further construction of large metallodendrimers up to G7 with approximately 14 000 organoiron termini was only possible by combining amide, "click", and tether lengthening strategies to avoid steric bulk at the dendrimer periphery. Reduction of the 18-electron FeII metallodendrimers, exemplified by a G4-DAB-64-FeII complex, was achieved exergonically using the parent electron-reservoir complex [Fe(η5-C5H 5)(η6-C6Me6)], 1a, at ?30 °C in MeCN, which allowed further reduction of 64 equiv of C60 to C60·? using the 19-electron FeI metallodendrimer.