3335-97-5

Basic information

• Product Name: 2H-Indol-2-one, 1,3-dihydro-1-methyl-3-phenyl-
• CAS NO: 3335-97-5
• Molecular Formula: C15H13NO
• Molecular Weight: 223.274
• Mol File: 3335-97-5.mol
• Article Data: 36

Chemical Properties

• CAS DataBase Reference: 2H-Indol-2-one, 1,3-dihydro-1-methyl-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Indol-2-one, 1,3-dihydro-1-methyl-3-phenyl-(3335-97-5)
• EPA Substance Registry System: 2H-Indol-2-one, 1,3-dihydro-1-methyl-3-phenyl-(3335-97-5)

Safety Data

• Hazardous Substances Data: 3335-97-5(Hazardous Substances Data)

Upstream product

• 101102-57-2 2-bromo-N-methyl-N,2-diphenylacetamide 
• 74585-33-4 N-(2-chlorophenyl)-N-methyl-2-phenylacetic acid amide 
• 2990-05-8 N-(2-chlorophenyl)-2-phenylacetamide 
• 1555-80-2 phenylacetic anhydride 
• 16174-75-7 2-[2-(p-tolylsulfanyl)phenyl]acetic acid 
• 18698-96-9 o-iodophenylacetic acid 
• 103-80-0 phenylacetyl chloride 
• 932-32-1 N-methyl-2-chloroaniline 
• 153704-11-1 N-(2-bromophenyl)-N-methylacetamide 
• 108-90-7 chlorobenzene 
• 172470-07-4 1-Methyl-3-(2-p-tolylsulfanyl-phenyl)-1,3-dihydro-indol-2-one 
• 175467-46-6 2-diazo-N-methyl-N,2-diphenylacetamide 
• 41601-11-0 3-Methyl-5,5-diphenyl-3,5-dihydro-4H-1,2,3-triazol-4-on 
• 65117-33-1 2-chloro-N-methyl-N,2-diphenylacetamide 

Downstream Products

• 110436-51-6 benzoic acid-(1-methyl-3-phenyl-indol-2-yl ester) 
• 114164-43-1 3-(3-dimethylamino-propyl)-1-methyl-3-phenyl-indolin-2-one 
• 3336-00-3 3-benzyl-1-methyl-3-phenylindolin-2-one 
• 1092719-34-0 1-methyl-3-phenylindol-2-yl phenyl carbonate 
• 1351204-45-9 (R)-3-((R)-1-(benzyloxy)allyl)-1-methyl-3-phenylindolin-2-one 
• 1453221-36-7 C₂₃H₂₅NO₃ 
• 1610460-92-8 1-methyl-3-(4-methylbenzyl)-3-phenylindolin-2-one 
• 1610460-93-9 1-methyl-3-(naphthalen-1-ylmethyl)-3-phenylindolin-2-one 
• 67818-40-0 3-(2,4-dinitrophenyl)-1-methyl-3-phenylindolin-2-one 

Relevant articles and documents

Palladium(II) Complexes Bearing a Mixed Set of aNHC/Py/PR3/I2 Ligands: Applications in α-Arylation of Amide and Suzuki-Miyaura Coupling Reactions

Complexes possessing abnormal or mesoionic carbene (aNHC or MIC) ligands are finding widespread applicability in organometallic chemistry owing to their various catalytic applications. Palladium(II) complexes bearing a mixed aNHC/Py/PR3/I2

Silyl Cyanopalladate-Catalyzed Friedel-Crafts-Type Cyclization Affording 3-Aryloxindole Derivatives

3-Aryloxindole derivatives were synthesized through a Friedel-Crafts-type cyclization. The reaction was catalyzed by a trimethylsilyl tricyanopalladate complex generated in situ from trimethylsilyl cyanide and Pd(OAc) 2. Wide varieties of diethyl phosphates derived from N -arylmandelamides were converted almost quantitatively into oxindoles. When N, N -dibenzylamide was used instead of an anilide substrate, a benzo-fused δ-lactam was obtained. An oxindole product was subjected to substitution reactions to afford 3,3-diaryloxindoles with two different aryl groups.

Copper-Catalyzed Asymmetric Propargylic Alkylation with Oxindoles: Diastereo- A nd Enantioselective Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters

A copper-catalyzed asymmetric propargylic alkylation of propargylic acetates with 3-substituted oxindoles for the stereoselective construction of vicinal tertiary and all-carbon quaternary stereocenters in a 3,3-disubstituted oxindole skeleton has been realized. The reaction proceeded smoothly under the catalysis of Cu(MeCN)4PF6combined with a chiral tridentate ferrocenyl P,N,N ligand, leading to a broad range of optically active 3,3-disubstituted oxindoles in high yields and with excellent diastereo- A nd enantioselectivities.