333719-64-5

Basic information

• Product Name: (Ru((C₆H₅)3P)2(ClC₆H₄CHNNCONH₂)(CO)Cl)
• CAS NO: 333719-64-5
• Molecular Weight: 885.731
• Mol File: 333719-64-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Ru((C₆H₅)3P)2(ClC₆H₄CHNNCONH₂)(CO)Cl)(CAS DataBase Reference)
• NIST Chemistry Reference: (Ru((C₆H₅)3P)2(ClC₆H₄CHNNCONH₂)(CO)Cl)(333719-64-5)
• EPA Substance Registry System: (Ru((C₆H₅)3P)2(ClC₆H₄CHNNCONH₂)(CO)Cl)(333719-64-5)

Safety Data

• Hazardous Substances Data: 333719-64-5(Hazardous Substances Data)

Upstream product

• 32240-63-4 dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) 
• 5315-86-6 4-chlorobenzaldehyde semicarbazone 

Relevant articles and documents

Chemical control on the coordination mode of benzaldehyde semicarbazone ligands. Synthesis, structure, and redox properties of ruthenium complexes

Reaction of benzaldehyde semicarbazone (HL-R, where H is a dissociable proton and R is a substituent (R = OMe, Me, H, Cl, NO2) at the para position of the phenyl ring) with [Ru(PPh3)3Cl2] and [Ru(PPh3)2(CO)2Cl2] has afforded complexes of different types. When HL-NO2 and [Ru(PPh3)3Cl2] react in solution at ambient temperature, trans-[Ru(PPh3)2(L-NO2)Cl] is obtained. Its structure determination by X-ray crystallography shows that L-NO2 is coordinated as a tridentate C,N,O-donor ligand. When reaction between HL-NO2 and [Ru(PPh3)3Cl2] is carried out in refluxing ethanol, a more stable cis isomer of [Ru(PPh3)2(L-NO2)Cl] is obtained. The trans isomer can be converted to the cis isomer simply by providing appropriate thermal energy. Slow reaction of HL-R with [Ru- (PPh3)2(CO)2Cl2] in solution at ambient temperature yields 5-[Ru(PPh3)2(L-R)(CO)Cl] complexes. A structure determination of 5-[Ru(PPh3)2(L-NO2)(CO)Cl] shows that the semicarbazone ligand is coordinated as a bidentate N,O-donor, forming a five-membered chelate ring. When reaction between HL-R and [Ru(PPh3)2(CO)2Cl2] is carried out in refluxing ethanol, the 4-[Ru(PPh3)2(L-R)(CO)Cl] complexes are obtained. A structure determination of 4-[Ru(PPh3)2(L-NO2)(CO)Cl] shows that a semicarbazone ligand is bound to ruthenium as a bidentate N,O- donor, forming a four-membered chelate ring. All the complexes are diamagnetic (low-spin d6, S = 0). The trans- and cis-[Ru(PPh3)2(L-NO2)Cl] complexes undergo chemical transformation in solution. The 5- and 4-[Ru(PPh3)2(L-R)(CO)Cl] complexes show sharp NMR signals and intense MLCT transitions in the visible region. Cyclic voltammetry of the 5-[Ru(PPh3)2(L-R)(CO)Cl] and 4-[Ru(PPh3)2(L-R)(CO)Cl] complexes show the Ru-(II)-Ru(III) oxidation to be within 0.66-1.07 V. This oxidation potential is found to linearly correlate with the Hammett constant of the substituent R.