334-68-9 Usage
Description
1-Fluorododecane is a long chain 1-fluoroalkane that can be synthesized through various chemical reactions. It is derived from 1-dodecanol and undergoes further reactions to produce a mixture of 1-chlorododecane and 1-bromododecane. 1-FLUORODODECANE can also be prepared from 1-hydroxydodecane.
Uses
Used in Chemical Synthesis:
1-Fluorododecane is used as a starting material for the synthesis of various organic compounds. Its unique chemical properties make it a valuable intermediate in the production of different chemical products.
Used in Pharmaceutical Industry:
1-Fluorododecane is used as a reagent in the pharmaceutical industry for the development of new drugs. Its ability to undergo various chemical reactions allows for the creation of diverse drug candidates with potential therapeutic applications.
Used in Lubricant Industry:
1-Fluorododecane is used as a component in the formulation of lubricants due to its long chain structure and chemical stability. It contributes to the overall performance and longevity of lubricants used in various industrial applications.
Used in Surfactant Production:
1-Fluorododecane is utilized in the production of surfactants, which are essential in various industries such as cosmetics, detergents, and textiles. Its unique properties help improve the effectiveness of surfactants in these applications.
Used in Polymer Industry:
1-Fluorododecane is employed in the polymer industry as a monomer or a modifier to enhance the properties of polymers. Its incorporation can lead to improved characteristics such as increased stability, enhanced chemical resistance, and better mechanical properties.
Used in Solvent Applications:
1-Fluorododecane serves as a solvent in various chemical processes due to its ability to dissolve a wide range of substances. It is particularly useful in industries where specific solvation properties are required for reactions or separation processes.
Synthesis Reference(s)
Tetrahedron Letters, 28, p. 4733, 1987 DOI: 10.1016/S0040-4039(00)96612-7
Check Digit Verification of cas no
The CAS Registry Mumber 334-68-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,3 and 4 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 334-68:
(5*3)+(4*3)+(3*4)+(2*6)+(1*8)=59
59 % 10 = 9
So 334-68-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H25F/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
334-68-9Relevant articles and documents
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Pattison,Norman
, p. 2311,2315 (1957)
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Landini,D. et al.
, p. 428 - 430 (1974)
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Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor
González-Esguevillas, María,Miró, Javier,Jeffrey, Jenna L.,MacMillan, David W.C.
, p. 4222 - 4227 (2019/06/13)
Herein we disclose a deoxyfluorination of alcohols with an electrophilic fluorine source via visible-light photoredox catalysis. This radical-mediated C–F coupling is capable of fluorinating secondary and tertiary alcohols efficiently, complementing previously reported nucleophilic deoxyfluorination protocols.
Catalytic nucleophilic fluorination by an imidazolium ionic liquid possessing trialkylphosphine oxide functionality
Paramanik, Minakshmi,Singh, Rekha,Mukhopadhyay, Sulekha,Ghosh, Sunil K.
, p. 47 - 55 (2015/07/15)
Abstract The synthesis of a new alkylmethylimidazolium ionic liquid wherein the alkyl group is functionalized with dihexylphosphine oxide moiety at the terminal position has been achieved in four steps from 1-methylimidazole. This hybrid ionic liquid effectively catalyzed the nucleophilic fluorination of primary alkyl mesylates under mild conditions using CsF as the fluoride source with a faster rate compared to butylmethylimidazolium mesylate. The hybrid catalyst was recycled 5 times without compromising the yield and purity of the product. The nucleophilic fluorination has been used for the synthesis of diethyl 2-(5-fluoropentyl)-2-methyl malonate, a precursor of 18F isotopomer of an apoptosis imaging agent and the protected form of O-(2'-fluoroethyl)-l-tyrosine, a 18F isotopomer of a tumor imaging agent.
