335239-64-0

Basic information

• Product Name: Benzoic acid (2S,3R,4S,6S)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-difluoromethylene-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester
• Synonyms: Benzoic acid (2S,3R,4S,6S)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-difluoromethylene-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester
• CAS NO: 335239-64-0
• Molecular Weight: 444.548
• Mol File: 335239-64-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (2S,3R,4S,6S)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-difluoromethylene-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (2S,3R,4S,6S)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-difluoromethylene-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester(335239-64-0)
• EPA Substance Registry System: Benzoic acid (2S,3R,4S,6S)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-difluoromethylene-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester(335239-64-0)

Safety Data

• Hazardous Substances Data: 335239-64-0(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 2280-44-6 D-Glucose 
• 181480-92-2 C₂₇H₃₆O₈Si 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 4137-35-3 methyl 2,3-di-O-benzoyl-α-D-glucopyranoside 
• 6748-85-2 methyl 2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 

Relevant articles and documents

Highly regio- and stereo-selective alkyl substitution with copper reagents for the construction of chiral trifluoromethylated quaternary carbon centres

A new route for the asymmetric construction of quaternary carbon centres containing a trifluoromethyl group has been established using a highly regio- and stereo-selective SN2′ reaction of organocopper and organocuprate reagents with allylic mesylates 4 and 8.