33560-61-1Relevant articles and documents
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German,Gibson
, p. 110 (1940)
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EFFECT OF IONIC ASSOCIATION ON THE KINETICS OF THE REACTION OF TRIARYLMETHYL CATIONS WITH ALKALI-METAL ETHOXIDES IN MIXED SOLVETS
Sinev, V. V.,Strel'nikova, G. I.
, p. 987 - 992 (2007/10/02)
The kinetics of the reaction of triarylmethyl ions with sodium and potassium ethoxides in binary ethanol-dioxane and ethanol-benzene systems were studied by a spectrophotometric method.A method is proposed for the separation of the observed rate constants into ion and ion-pair components.It was shown that the effect of the solvent polarity on the ionic components of the kinetic parameters of reactions of the investigated type agrees quantitatively with electrostatic theory.