33603-90-6

Basic information

• Product Name: 2-Propenal, 2-bromo-3-phenyl-, (Z)-
• CAS NO: 33603-90-6
• Molecular Formula: C₉H₇BrO
• Molecular Weight: 211.058
• Mol File: 33603-90-6.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: 2-Propenal, 2-bromo-3-phenyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenal, 2-bromo-3-phenyl-, (Z)-(33603-90-6)
• EPA Substance Registry System: 2-Propenal, 2-bromo-3-phenyl-, (Z)-(33603-90-6)

Safety Data

• Hazardous Substances Data: 33603-90-6(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 104-55-2 3-phenyl-propenal 
• 115-17-3 bromal 
• 100-52-7 benzaldehyde 
• 108-24-7 acetic anhydride 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 99686-39-2 (E)-2-bromo-3-phenylprop-2-enal 
• 85371-47-7 β,β-dibromovinyl methyl ether 
• 66894-04-0 2,3-dibromo-3-phenyl propanal 

Downstream Products

• 86517-23-9 (2S,3S)-2,3-Di-morpholin-4-yl-3-phenyl-propionaldehyde 
• 869732-37-6 ethyl (2E,4Z)-4-bromo-5-phenylpenta-2,4-dienoate 
• 4364-05-0 (Z)-(2-bromo-3,3-diethoxyprop-1-en-1-yl)benzene 
• 1218805-51-6 C₂₂H₁₄Cl₂N₂O 
• 1218805-53-8 C₂₂H₁₅N₃O₃ 
• 1218805-55-0 C₂₂H₁₅ClN₂O 
• 1218805-49-2 C₂₃H₁₈N₂O₂ 
• 1311273-14-9 (E)-2-benzylidene-4-(4-chlorophenyl)-1-phenylbut-3-yn-1-ol 
• 1311273-16-1 (E)-2-benzylidene-4-(cyclohexen-1-yl)-1-phenylbut-3-yn-1-ol 
• 1311273-18-3 (E)-2-benzylidene-1-(4-chlorophenyl)-4-phenylbut-3-yn-1-ol 
• 1311273-19-4 (Z)-2-(2-benzylidene-1,4-diphenylbut-3-ynyl)-5-methylfuran 
• 1311273-20-7 (Z)-2-(2-benzylidene-1,4-diphenylbut-3-ynyl)-5-phenylfuran 
• 1311273-21-8 (Z)-5-(2-benzylidene-1,4-diphenylbut-3-ynyl)-2,3-dimethylfuran 
• 1311273-22-9 (Z)-2-(2-benzylidene-1,4-diphenylbut-3-ynyl)furan 

Relevant articles and documents

4-exo-dig cyclocarbopalladation: A straightforward synthesis of cyclobutanediols from acyclic γ-bromopropargylic diols under microwave irradiation conditions

Treatment of acyclic γ-bromopropargylic diols with tributyl-stannylated alkynes under palladium catalysis and microwave irradiation conditions gives high yields of the bis(alkylidene)cyclobutanediol derivatives and cyclobutenediols through an efficient 4-exo-dig cyclocarbopalladation. The cyclization is general with a wide variety of alkyne derivatives and gives access to new cyclobutane ring systems bearing one exocyclic double bond and one eneyne substituent as well as bicyclic dienes sharing a common double bond that may be of interest for further elaborations of complex molecules. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

Stereodivergent synthesis of 2-alkynyl buta-1,3-dienes using Sonogashira coupling with controllable retention or inversion of olefin geometry

A stereodivergent approach to 2-alkynyl buta-1,3-dienes from a single stereoisomer of starting α-bromoenal has been developed. By simply switching the sequence of Sonogashira and Horner-Wadsworth-Emmons reactions, it is possible to obtain these branched d

DMAP-Catalyzed C—N Bond Formation for Diverse Synthesis of Imidazo[1,2-a]pyrimidine and Pyrimido[1,2-a]benzimidazole Derivatives

A DMAP (2-dimethylaminopyridine)-catalyzed condensation reactions for the successful direct construction of pyrimido[1,2-a]benzimidazole or imidazo[1,2-a]pyrimidine has been developed. The method utilizes readily available α-bromocinnamaldehydes with 2-am