33766-43-7Relevant articles and documents
FURTHER 5-METHYL COUMARINS AND OTHER CONSTITUENTS FROM THE SUBTRIBE MUTISINAE
Zredo, C.,Bohlmann, F.,King, R. M.,Robinson, H.
, p. 509 - 516 (1986)
Key Word Index-Mutisia spinosa, M. retorsa; Trichocline sinuata; Brachyclados megalanthus; Compositae; chemotaxonomy; 5-methyl coumarins; monoterpenes; geraniol and linalol derivatives; C14-acetylenic compound.The investigation of four species from the subtribe Mutisiinae afforded eight new monoterpenes, seven 5-methyl coumarins, two closely related 5-methyl chromones, two coumarane derivatives, a p-hydroxy acetophenone derivative and a new C14-acetylene.The structures were elucidated by spectroscopic methods and a few chemical transformations.The chemotaxonomy of the Mutisiinae is discussed.
Selective isomerization of epoxides to allylic alcohols catalyzed by TiO2-supported gold nanoparticles
Raptis, Christos,Stratakis, Manolis,Garcia, Hermenegildo
experimental part, p. 3133 - 3136 (2009/09/25)
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Chemical transformation of terpenoids. VIII. Anodic oxidation of geranyl acetate
Shibuya,Murakami,Shimada,Kitagawa
, p. 1302 - 1304 (2007/10/02)
Constant-current electrolysis of geranyl acetate (2) in CH3CN-H2O afforded eight oxidation products (3-10) which were presumed to be formed through initial oxidation of the double bond at C6-C7. Based on the results of electrolysis of 2 in CH3CN-H218O we have found that the oxygen atom(s) in the products (3-10) is(are) derived from water used as the reaction medium.