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3377-87-5

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3377-87-5 Usage

Uses

3-Bromohexane is used as a pharmaceutical intermediate.

Check Digit Verification of cas no

The CAS Registry Mumber 3377-87-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,3,7 and 7 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 3377-87:
(6*3)+(5*3)+(4*7)+(3*7)+(2*8)+(1*7)=105
105 % 10 = 5
So 3377-87-5 is a valid CAS Registry Number.
InChI:InChI=1/C6H13Br/c1-3-5-6(7)4-2/h6H,3-5H2,1-2H3

3377-87-5 Well-known Company Product Price

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  • Alfa Aesar

  • (L00818)  3-Bromohexane, 97%   

  • 3377-87-5

  • 5g

  • 347.0CNY

  • Detail
  • Alfa Aesar

  • (L00818)  3-Bromohexane, 97%   

  • 3377-87-5

  • 25g

  • 1256.0CNY

  • Detail

3377-87-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-BROMOHEXANE

1.2 Other means of identification

Product number -
Other names 3-Bromohexane (contains 2-Bromohexane)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3377-87-5 SDS

3377-87-5Relevant articles and documents

Catalytic Bromination of Alkyl sp3C-H Bonds with KBr/Air under Visible Light

Zhao, Mengdi,Lu, Wenjun

supporting information, p. 5264 - 5267 (2018/09/12)

Alkyl sp3C-H bonds of cycloalkanes and functional branch/linear alkanes have been successfully brominated with KBr using air or O2 as an oxidant at room temperature to 40 °C. The reactions are carried out in the presence of catalytic NaNO2 in 37% HCl (aq)/solvent under visible light, combining aerobic oxidations and photochemical radical processes. For various alkane substrates, CF3CH2OH, CHCl3, or CH2Cl2 is employed as an organic solvent, respectively, to enhance the efficiency of bromination.

Tetrabutylphosphonium Bromide Catalyzed Dehydration of Diols to Dienes and Its Application in the Biobased Production of Butadiene

Stalpaert, Maxime,Cirujano, Francisco G.,De Vos, Dirk E.

, p. 5802 - 5809 (2017/09/15)

We report the use of the ionic liquid tetrabutylphosphonium bromide as a solvent and catalyst for dehydration of diols to conjugated dienes. This system combines stability, high reaction rates, and easy product separation. A reaction mechanism for the model compound 1,2-hexanediol is proposed and experimentally corroborated. This particular mechanism allows for the selective formation of conjugated dienes, in contrast with purely acidic catalysis. Next, the reaction is also performed on various other diols. As a first application, we assessed the biobased production of 1,3-butadiene. With 1,4-butanediol as the starting material, a 94% yield of butadiene was reached at 100% conversion.

Site-selective aliphatic C-H bromination using N -bromoamides and visible light

Schmidt, Valerie A.,Quinn, Ryan K.,Brusoe, Andrew T.,Alexanian, Erik J.

supporting information, p. 14389 - 14392 (2014/12/10)

Transformations that selectively functionalize aliphatic C-H bonds hold significant promise to streamline complex molecule synthesis. Despite the potential for site-selective C-H functionalization, few intermolecular processes of preparative value exist. Herein, we report an approach to unactivated, aliphatic C-H bromination using readily available N-bromoamide reagents and visible light. These halogenations proceed in useful chemical yields, with substrate as the limiting reagent. The site selectivities of these radical-mediated C-H functionalizations are comparable (or superior) to the most selective intermolecular C-H functionalizations known. With the broad utility of alkyl bromides as synthetic intermediates, this convenient approach will find general use in chemical synthesis.

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