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338-83-0

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  • High Quality 99% 1-Propanamine,1,1,2,2,3,3,3-heptafluoro-N,N-bis(1,1,2,2,3,3,3-heptafluoropropyl)- 338-83-0 ISO Manufacturer

    Cas No: 338-83-0

  • USD $ 0.1-0.1 / Gram

  • 1 Gram

  • 100 Metric Ton/Year

  • Xi'an Xszo Chem Co., Ltd.
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338-83-0 Usage

Description

Perfluorotripropylamine is a chemical compound with the formula C9F21N, characterized by its unique perfluorinated structure and amine functional group. It possesses properties such as low surface tension, high thermal stability, and resistance to chemical degradation, making it a versatile reagent for various applications.

Uses

Used in Microfluidics:
Perfluorotripropylamine is used as a reagent for surface modification in droplet polymeric microfluidic devices. Its application is crucial for improving the stable and continuous generation of aqueous droplets, which is essential for the efficient functioning of microfluidic systems.
Used in Surface Coating Industry:
Perfluorotripropylamine is used as a surface-active agent in the development of coatings with enhanced properties. Its low surface tension and chemical resistance contribute to the formation of uniform and durable coatings, which are particularly useful in applications requiring non-stick, anti-fouling, or easy-to-clean surfaces.
Used in Chemical Synthesis:
Perfluorotripropylamine serves as an intermediate or reactant in the synthesis of various perfluorinated compounds. Its unique structure and reactivity make it a valuable building block for the development of specialty chemicals, pharmaceuticals, and materials with tailored properties.
Used in Electronics Industry:
Perfluorotripropylamine is utilized as a component in the fabrication of electronic devices, particularly in the development of high-performance lubricants and thermal interface materials. Its thermal stability and resistance to degradation contribute to the reliable operation and longevity of electronic components.
Used in Environmental Remediation:
Perfluorotripropylamine is employed in the treatment of contaminated water and soil, where its chemical properties enable the efficient removal of pollutants and the decontamination of affected environments. Its resistance to degradation and low toxicity make it a suitable candidate for environmental applications.

Purification Methods

Purify it as for perfluorodimethyl-cyclopropane (see p 220). [Haszeldine J Chem Soc 102 1951, for azeotropes see Simons & Linevsky J Am Chem Soc 74 4750 1972.] IRRITANT.

Check Digit Verification of cas no

The CAS Registry Mumber 338-83-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,3 and 8 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 338-83:
(5*3)+(4*3)+(3*8)+(2*8)+(1*3)=70
70 % 10 = 0
So 338-83-0 is a valid CAS Registry Number.

338-83-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name perfluorotripropylamine

1.2 Other means of identification

Product number -
Other names 1-Propanamine,1,1,2,2,3,3,3-heptafluoro-N,N-bis(heptafluoropropyl)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:338-83-0 SDS

338-83-0Synthetic route

tri-n-propylamine
102-69-2

tri-n-propylamine

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

Conditions
ConditionsYield
With fluorine; sodium fluoride In 1,1,2-Trichloro-1,2,2-trifluoroethane at 10℃; for 5h;72.5%
With hydrogen fluoride at -4 - 19℃; Product distribution; Electrochemical fluorination. Var. temp., voltage, init conc. of amine, stirring effect investigated.;
With cobalt (III) fluoride at 300℃;
tri-n-propylamine
102-69-2

tri-n-propylamine

A

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

B

N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine
97147-06-3

N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine

Conditions
ConditionsYield
With hydrogen fluoride at 3 - 6℃; for 52h; electrochemical fluorination;A 20.1%
B 2.1%
perfluoropropylene
116-15-4

perfluoropropylene

di-n-propylamine
142-84-7

di-n-propylamine

A

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

B

N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine
97147-06-3

N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine

Conditions
ConditionsYield
With hydrogen fluoride 1.) ether, room temperature, overnight, 2.) electrochemical fluorination, 3-6 deg C, 52 h; Yield given. Multistep reaction. Yields of byproduct given;
heptafluoropropyl-bis-(1,2,2,3,3,3-hexafluoro-propyl)-amine

heptafluoropropyl-bis-(1,2,2,3,3,3-hexafluoro-propyl)-amine

A

carbon tetrafluoride
75-73-0

carbon tetrafluoride

B

freon-218
76-19-7

freon-218

C

Hexafluoroethane
76-16-4

Hexafluoroethane

D

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

Conditions
ConditionsYield
With fluorine at 280 - 390℃; for 0.1h; Fluorination; Title compound not separated from byproducts;
With fluorine at 100 - 170℃; for 17h; Product distribution; Further Variations:; Temperatures; time; Fluorination;
tri-n-propylamine
102-69-2

tri-n-propylamine

nitrogen

nitrogen

cobalt (III)-fluoride

cobalt (III)-fluoride

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

Conditions
ConditionsYield
at 300℃;
tri-n-propylamine
102-69-2

tri-n-propylamine

A

freon-218
76-19-7

freon-218

B

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

C

F-(N-F-Fluoro,N,N-di-n-propylamine)
1554-24-1

F-(N-F-Fluoro,N,N-di-n-propylamine)

D

2,3,3,4,4,5-hexafluoro-1,2-bis-pentafluoroethyl-5-trifluoromethyl-pyrrolidine

2,3,3,4,4,5-hexafluoro-1,2-bis-pentafluoroethyl-5-trifluoromethyl-pyrrolidine

Conditions
ConditionsYield
With hydrogen fluoride Product distribution; Further Variations:; current density; Electrochemical reaction;
Triallylamine
102-70-5

Triallylamine

toluene
108-88-3

toluene

A

perfluoro-(N-propyl-3,4-dimethylpyrrolidine)
413579-52-9

perfluoro-(N-propyl-3,4-dimethylpyrrolidine)

B

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

C

perfluoro-(N-propyl-3-methylpiperidine)
96009-90-4

perfluoro-(N-propyl-3-methylpiperidine)

D

perfluoro-(1,2-dimethylcyclopentane)

perfluoro-(1,2-dimethylcyclopentane)

E

perfluoro-(1,1-dimethylcyclopentane)

perfluoro-(1,1-dimethylcyclopentane)

F

perfluoro-(ethylcyclopentane)

perfluoro-(ethylcyclopentane)

Conditions
ConditionsYield
With hydrogen fluoride Electrochemical reaction; Further byproducts. Title compound not separated from byproducts.;
tri-n-propylamine
102-69-2

tri-n-propylamine

hydrogen fluoride
7664-39-3

hydrogen fluoride

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); Electrochem. Process; electrofluorination, 4-8 V, 200 A/m2, Ni anode, Fe cathode;
tri-n-propylamine
102-69-2

tri-n-propylamine

cobalt(III) fluoride
10026-18-3

cobalt(III) fluoride

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

difluoromethylene-heptafluoropropyl-amine
378-00-7

difluoromethylene-heptafluoropropyl-amine

Conditions
ConditionsYield
pyrolysis at 660-670°C in graphite tube;82%
pyrolysis at 660-670°C;73%
pyrolysis at 660-670°C in presence of AlF3;>99
Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

2,2,3,3,3-pentafluoro-N-(perfluoropropyl)propanimidoyl fluoride
356-64-9

2,2,3,3,3-pentafluoro-N-(perfluoropropyl)propanimidoyl fluoride

Conditions
ConditionsYield
With antimony pentafluoride at 70 - 110℃; for 3h;63%
passing through a graphite tube filled with AlF3-Al2O3, at 500-550°C;
With β-Al2O3/AlF3 at 550℃;
Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

perfluoro(2-aza-2-pentene)
680-23-9

perfluoro(2-aza-2-pentene)

Conditions
ConditionsYield
at 650℃;15.6 g
Perfluorotripropylamine
338-83-0

Perfluorotripropylamine

o-carborane

o-carborane

A

3,3,3-trifluoro-2,2-difluoropropylamide of perfluorobutanoic acid

3,3,3-trifluoro-2,2-difluoropropylamide of perfluorobutanoic acid

B

8,9,10,12-tetrafluoro-o-carborane

8,9,10,12-tetrafluoro-o-carborane

Conditions
ConditionsYield
With water; antimony pentafluoride 1.) 70 deg C, 10 h; Yield given. Multistep reaction;

338-83-0Downstream Products

338-83-0Relevant articles and documents

CORRELATION BETWEEN YIELD AND OPERATING CONDITIONS IN THE ELECTROCHEMICAL FLUORINATION OF TRIPROPYLAMINE

Conte, L.,Napoli, M.,Gambaretto, G. P.

, p. 89 - 96 (1985)

Electrochemical fluorination of tripropylamine in anhydrous hydrogen fluoride was studied in order to verify the correlation between the operating conditions and the yield of the corresponding perfluoroamine.The parameters tested were: temperature, voltage, initial concentration of amine in the bath, constant concentration of amine in the bath and stirring effect.Experimental data show that temperature is the parameter exerting the most remarkable influence over perfluoroamine yield and by-products formation.

An efficient high-yield synthesis for perfluorinated tertiary alkyl amines

Felling, Kyle W.,Lagow, Richard J.

, p. 233 - 236 (2007/10/03)

We wish to report a high-yield synthesis of perfluorinated tertiary amines from their hydrocarbon analogues by direct fluorination. Yields up to 70%, with high purities, have been obtained from certain tertiary amines. This technique will likely develop into a new general method for producing perfluorinated amines.

Technology for the preparation of perfluoro-organic compounds

Moldavskii, Dmitrii D.,Bispen, Tatjana A.,Kaurova, Galina I.,Furin, Georgii G.

, p. 157 - 167 (2007/10/03)

Fluorination by elemental fluorine of fluorine-containing alkenes, alkanes, ethers and tertiary amines was investigated, aimed at obtaining the perfluorinated analogs. The factors affecting yield of the target compounds were studied. Elements of technology were elucidated.

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