339525-69-8

Basic information

• Product Name: C₆H₃(CH₂N(CH₃)2)(OCH₃)AuNC₆H₅(COCHCOC₆H₅)
• CAS NO: 339525-69-8
• Molecular Weight: 598.452
• Mol File: 339525-69-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₃(CH₂N(CH₃)2)(OCH₃)AuNC₆H₅(COCHCOC₆H₅)(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₃(CH₂N(CH₃)2)(OCH₃)AuNC₆H₅(COCHCOC₆H₅)(339525-69-8)
• EPA Substance Registry System: C₆H₃(CH₂N(CH₃)2)(OCH₃)AuNC₆H₅(COCHCOC₆H₅)(339525-69-8)

Safety Data

• Hazardous Substances Data: 339525-69-8(Hazardous Substances Data)

Upstream product

• 181886-26-0 AuCl₂(4-methoxy-N,N-dimethylbenzylamine) 
• 959-66-0 3-oxo-3-phenylpropionanilide 

Relevant articles and documents

Synthesis and characterisation of four- and eight-membered ring auralactam complexes

The reactions of the cyclo-aurated gold(III) dihalide complex [{C6H3(CH2NMe2)-2-(OMe)-5}AuCl 2] with N-cyanoacety-lurethane [NCCH2C(O)NHCO2Et], 2-benzoylacetanilide [PhC(O)CH2C(O)NHPh] and acetoacetanilide [MeC(O)CH2C(O)NHPh], and [{C6H4(CH2NMe2)-2}AuCl2] with acetoacetanilide in dichloromethane with excess silver(I) oxide gives the first examples of auralactam complexes, containing Au-NR-C(O)-CHR′ four-membered rings. A single-crystal X-ray diffraction study on the complex [{C6H4(CH2NMe 2)-2}Au{NPhC(O)CH(COMe)}] reveals similar structural features to related metallalactam complexes of platinum(II) and palladium(II). When a CDCl3 solution of the complex [{C6H3(CH2NMe 2)-2-(OMe)-5}Au{N(CO2Et)C(O)CHCN}] is allowed to stand for 18 h, a novel dimerisation reaction occurs, giving the insoluble product [{C6H3(CH2NMe 2)-2-(OMe)-5}Au{N(CO2Et)C(O)CHCN}] 2·2CDCl3, characterised by an X-ray structure determination. The dimer contains an eight-membered Au-N-C(O)-C-Au-N-C(O)-C ring.