33974-39-9

Basic information

• Product Name: 2,6-di-tert-butyl-4,4-dimethoxycyclohexa-2,5-dien-1-one
• Synonyms: 2,6-di-tert-butyl-4,4-dimethoxycyclohexa-2,5-dien-1-one
• CAS NO: 33974-39-9
• Molecular Weight: 266.381
• Mol File: 33974-39-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,6-di-tert-butyl-4,4-dimethoxycyclohexa-2,5-dien-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-di-tert-butyl-4,4-dimethoxycyclohexa-2,5-dien-1-one(33974-39-9)
• EPA Substance Registry System: 2,6-di-tert-butyl-4,4-dimethoxycyclohexa-2,5-dien-1-one(33974-39-9)

Safety Data

• Hazardous Substances Data: 33974-39-9(Hazardous Substances Data)

Upstream product

• 195198-12-0 p-methoxybenzyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)thiomethyl-7-phenylacetamido-Δ3-cephem-4-carboxylate 
• 67-56-1 methanol 
• 489-01-0 2,6-Di-t-butyl-4-methoxyphenol 

Relevant articles and documents

Chemo- and product-selective electrooxidation of 3-(arylthiomethyl)- Δ3-cephems

Electrolysis of 3-arylthiomethyl-Δ3-cephems possessing various substituents on the arylthio moiety undergo chemo selective and product-selective electrooxidation to give several different products. These include isomeric mixtures of the corresponding methoxylated cephems, a bis[(Δ3-cephem-3-yl)methyl]disulfide or a 3-dimethoxymethyl- Δ3-cephem. The selectivity of the oxidation is highly dependent on the nature of the substituents on the arylthio moiety which suggests that both steric and electronic effects play an important role in the electrooxidation of 3-arylthiomethyl-Δ3-cephems.