34147-85-8Relevant articles and documents
Synergistic effect in the catalysis by pyridine N-oxide-triethylamine mixture of acyl transfer processes with participation of benzoyl, diethoxyphosphinoyl, and p-toluenesulfonyl chlorides
Belousova,Savelova,Simanenko,Panchenko
, p. 111 - 114 (2002)
The kinetics of benzoylation of substituted phenols with benzoyl chloride in the presence of pyridine N-oxide-triethylamine was analyzed with regard to previously reported data on benzoylation, phosphorylation, and sulfonylation of phenols and carboxylic acids. A common mechanism of the synergistic effect was established. The synergistic effect decreases in the series PhCOCl (EtO)2POCl > TsCl.