34151-51-4

Basic information

• Product Name: N,N’-bis(4-pyridylmethyl)-1,4,5,8-naphthalenetetra-carboxydiimide
• Synonyms: N,N’-bis(4-pyridylmethyl)-1,4,5,8-naphthalenetetra-carboxydiimide
• CAS NO: 34151-51-4
• Molecular Weight: 448.437
• Mol File: 34151-51-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: N,N’-bis(4-pyridylmethyl)-1,4,5,8-naphthalenetetra-carboxydiimide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N’-bis(4-pyridylmethyl)-1,4,5,8-naphthalenetetra-carboxydiimide(34151-51-4)
• EPA Substance Registry System: N,N’-bis(4-pyridylmethyl)-1,4,5,8-naphthalenetetra-carboxydiimide(34151-51-4)

Safety Data

• Hazardous Substances Data: 34151-51-4(Hazardous Substances Data)

Upstream product

• 3731-53-1 4-(aminomethyl)pyridine 
• 81-30-1 1,4,5,8-naphthalenetetracarboxylic dianhydride 
• 5690-24-4 1,4,5,8-naphthalenetetracaraboxylic dianhydride 

Relevant articles and documents

Electronic, optical, and computational studies of a redox-active napthalenediimide-based coordination polymer

The new one-dimensional coordination framework (Zn(DMF)NO3) 2(NDC)(DPMNI), where NDC = 2,6-naphthalenedicarboxylate and DPMNI = N,N′-bis(4-pyridylmethyl)-1,4,5,8-naphthalenetetracarboxydiimide, which has been crystallographically characterized, exhibits two redox-accessible states due to the successive reduction of the naphthalenediimide (NDI) ligand core. Solid-state electrochemical and vis-near-IR spectroelectrochemical measurements coupled with density functional theory (DFT) calculations enabled the origins of the optical transitions in the spectra of the monoradical anion and dianion states of the material to be assigned. Electron paramagnetic resonance (EPR) spectroscopy revealed that the paramagnetic radical anion state of the DPMNI core could be accessed upon broad-spectrum white light irradiation of the material, revealing a long-lived excited state, possibly stabilized by charge delocalization which arises from extensive π-π* stacking interactions between alternating NDC and NDI aromatic cores which are separated by a distance of 3.580(2) A.

Co(II)-based Metal-Organic Frameworks and Their Application in Gas Sorption and Solvatochromism

We report the synthesis and structural characterization of a unique Co-MOF-1 with the formula [Co2(dpmndi)(bdc)2)]·DMF; (dpmndi = N,N′-bis(4-pyridylmethyl)-1,4,5,8-naphthalenediimide and bdc = benzene-1,4-dicarboxylate) along with an

Supramolecular structural transformation of: N, N ′-bis(4-pyridylmethyl)-naphthalene diimide and fluorescence water sensing

A supramolecular structure based on N,N′-bis(4-pyridylmethyl)-naphthalene diimide exhibits reversible phase transitions in a single-crystal-to-single-crystal process. Such temperature induced SC-SC transformations are driven by intermolecular π-π interactions and hydrogen bond interaction. Interestingly, the dynamic supramolecular structure shows selective adsorption and fluorescence water sensing.