3416-49-7

Basic information

• Product Name: Benzenamine, N-butyl-N-methyl-
• CAS NO: 3416-49-7
• Molecular Formula: C11H17N
• Molecular Weight: 163.263
• Mol File: 3416-49-7.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-butyl-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-butyl-N-methyl-(3416-49-7)
• EPA Substance Registry System: Benzenamine, N-butyl-N-methyl-(3416-49-7)

Safety Data

• Hazardous Substances Data: 3416-49-7(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 1126-78-9 N-(n-butyl)aniline 
• 123-72-8 butyraldehyde 
• 100-61-8 N-methylaniline 
• 542-69-8 1-iodo-butane 
• 109-69-3 n-Butyl chloride 
• 74-88-4 methyl iodide 
• 57361-03-2 (E/Z)-2-(N-Methylanilino)-2-pentennitril 
• 110-68-9 N-n-butyl-N-methylamine 
• 108-86-1 bromobenzene 
• 614-30-2 N-methyl-N-phenyl-benzenemethanamine 
• 124-38-9 carbon dioxide 
• 103-84-4 Acetanilid 
• 64-18-6 formic acid 

Downstream Products

• 13475-69-9 N-butyl-N-methyl-2-nitrobenzenamine 
• 56269-49-9 N-butyl-N-methyl-4-nitrobenzenamine 
• 1079-83-0 4-(butyl(methyl)amino)benzaldehyde 
• 614-00-6 N-methyl-N-nitrosoaniline 
• 943-41-9 N-methyl-N-nitroso-4-nitroaniline 
• 156808-76-3 4-bromo-N-butyl-N-methylaniline 
• 25413-69-8 N-butyl-N-nitroso-aniline 
• 366-29-0 N,N,N',N'-tetramethylbenzidine 
• 7137-77-1 N,N-dimethyl-4-{[methyl(phenyl)amino]methyl}aniline 
• 1126-78-9 N-(n-butyl)aniline 
• 479-45-8 tetryl 
• 408507-92-6 N-butyl-N-methyl-4-nitroso-aniline 

Relevant articles and documents

Dirhodium-Catalyzed Chemo-and Site-Selective C-H Amidation of N, N-Dialkylanilines

A method for dirhodium-catalyzed C(sp 3)-H amidation of N, N-dimethylanilines was developed. Chemoselective C(sp 3)-H amidation of N-methyl group proceeded exclusively in the presence of C(sp 2)-H bonds of the electron-rich aromatic ring. Site-selective C(sp 3)-H amidation proceeded exclusively at the N-methyl group of N-methyl-N-Alkylaniline derivatives with secondary, tertiary, and benzylic C(sp 3)-H bonds α to a nitrogen atom.

Visible light-induced N-methyl activation of unsymmetric tertiary amines

In the presence of methylene group, selective N-methyl activation of tertiary amines has been accomplished with the aid of visible light using organic photocatalyst under air. This protocol explores numerous aliphatic and aromatic substituted tetra-hydroquinoline analogues from various tertiary amines and maleimides. Furthermore, this approach was applied to activate the methyl group of N-methyl carbazole to generate the biologically active molecule.

Mn-Catalyzed Selective Double and Mono-N-Formylation and N-Methylation of Amines by using CO2

Functionalization of amines by using CO2 is of fundamental importance considering the abundance of amines and CO2. In this context, the catalytic formylation and methylation of amines represent convenient and successful protocols for selective CO2 utilization as a C1 building block. This study represents the first example of selective catalytic double N-formylation of aryl amines by using a dinuclear Mn complex in the presence of phenylsilane. This robust system also allows for selective formylation and methylation of amines under a range of conditions.