34277-73-1Relevant articles and documents
Synthesis of acyl carbamates via four component Pd-catalyzed carbonylative coupling of aryl halides, potassium cyanate, and alcohols
Yin, Hongfei,De Almeida, Angelina M.,De Almeida, Mauro V.,Lindhardt, Anders T.,Skrydstrup, Troels
, p. 1248 - 1251 (2015)
A simple and mild method is demonstrated for assembling acyl carbamates through a base-free four-component Pd-catalyzed carbonylation of aryl halides in the presence of potassium cyanate and alcohols in a two-chamber system. This approach produces a wide range of aryl acyl carbamates in good to excellent yields from the corresponding aryl bromides or iodides with near-stoichiometric carbon monoxide. In addition, the method can be extended to the synthesis of primary amides thereby expanding the usefulness of cyanate as an ammonia equivalent.
Reaction of TPP-azodicarboxylate zwitterions and aryl aldehydes: unprecedented synthesis of acyl carbamates
Nair, Vijay,Mathew, Smitha C.,Biju,Suresh
, p. 9018 - 9020 (2008/03/18)
An efficient synthesis of acyl carbamates from aryl aldehydes by the reaction of triphenylphosphine and dialkyl azoesters is described.
